Molecular Main Group Metal Hydrides

Matthew  Roy; Alvaro Omana; Andrew Wilson; Michael Hill; Simon Aldridge; Eric Rivard

doi:10.1021/acs.chemrev.1c00278

Molecular Main Group Metal Hydrides

Matthew Roy, Alvaro Omana, Andrew Wilson, Michael Hill, Simon Aldridge, Eric Rivard

Research output: Contribution to journal › Review article › peer-review

116 Citations (SciVal)

Abstract

This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.

Original language	English
Pages (from-to)	12784-12965
Number of pages	182
Journal	Chemical Reviews
Volume	121
Issue number	20
Early online date	27 Aug 2021
DOIs	https://doi.org/10.1021/acs.chemrev.1c00278
Publication status	Published - 27 Oct 2021

ASJC Scopus subject areas

Chemistry(all)

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10.1021/acs.chemrev.1c00278

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title = "Molecular Main Group Metal Hydrides",

abstract = "This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.",

author = "Matthew Roy and Alvaro Omana and Andrew Wilson and Michael Hill and Simon Aldridge and Eric Rivard",

note = "Funding Information: E.R. thanks NSERC of Canada for Discovery and Accelerator Supplement Grants. M.M.D.R. thanks NSERC of Canada for a Postdoctoral Fellowship. Publisher Copyright: {\textcopyright} 2021 American Chemical Society. All rights reserved.",

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AU - Roy, Matthew

AU - Omana, Alvaro

AU - Wilson, Andrew

AU - Hill, Michael

AU - Aldridge, Simon

AU - Rivard, Eric

N1 - Funding Information: E.R. thanks NSERC of Canada for Discovery and Accelerator Supplement Grants. M.M.D.R. thanks NSERC of Canada for a Postdoctoral Fellowship. Publisher Copyright: © 2021 American Chemical Society. All rights reserved.

PY - 2021/10/27

Y1 - 2021/10/27

N2 - This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.

AB - This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.

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JO - Chemical Reviews

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ER -

Molecular Main Group Metal Hydrides

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Nucleophilic alkaline earth boryls: from conception and theory to application

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Molecular Main Group Metal Hydrides

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Nucleophilic alkaline earth boryls: from conception and theory to application

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