TY - JOUR
T1 - Mixed‐Anion Aggregates of Metalated Organics
T2 - Preparation and Structure of the Mixed‐Anion Tetramer (PhO⊖Li⊕ · HMPA)3(μ3‐HMPA · Li⊕)NCS⊖
AU - Raithby, Paul R.
AU - Reed, David
AU - Snaith, Ronald
AU - Wright, Dominic S.
PY - 1991/8/31
Y1 - 1991/8/31
N2 - Combination of the ammonium salt method and normal metalation makes it possible to construct in a controlled fashion the inorganic/organic lithium complex 1. BuLi, NH4NCS, phenol, and HMPA (4: 1 : 3 : 4) in toluene afforded the air‐sensitive compound 1 in over 60% yield. Compound 1 contains three terminal HMPA ligands and one terminal NCS ligand as well as three μ3‐bridging PhO ligands and one μ3‐bridging HMPA ligand. The analogous complex containing four PhO ligands and no NCS ligand was also synthesized. The latter is completely inert toward water and air. (Figure Presented.)
AB - Combination of the ammonium salt method and normal metalation makes it possible to construct in a controlled fashion the inorganic/organic lithium complex 1. BuLi, NH4NCS, phenol, and HMPA (4: 1 : 3 : 4) in toluene afforded the air‐sensitive compound 1 in over 60% yield. Compound 1 contains three terminal HMPA ligands and one terminal NCS ligand as well as three μ3‐bridging PhO ligands and one μ3‐bridging HMPA ligand. The analogous complex containing four PhO ligands and no NCS ligand was also synthesized. The latter is completely inert toward water and air. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748231375&partnerID=8YFLogxK
U2 - 10.1002/anie.199110111
DO - 10.1002/anie.199110111
M3 - Article
AN - SCOPUS:33748231375
SN - 0570-0833
VL - 30
SP - 1011
EP - 1013
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 8
ER -