Mixed solvents in gas-liquid chromatography. Activity coefficients for diethyl ether in squalane and dinonyl phthalate mixtures at 303°K

Anthony J. Ashworth, Trevor M. Letcher, Gareth J. Price

Research output: Contribution to journalArticle

Abstract

Activity and partition coefficients for the polar solute diethyl ether at infinite dilution in squalane and dinonyl phthalate solvent mixtures have been determined at 303°K by the extrapolation of measurements made using a vacuum microbalance technique. The results are compared to predictions using the Purnell-Andrade and the Tiley-Perry relationships. The effect on the activity coefficients resulting from various solvent-solid support ratios has also been investigated.

Original languageEnglish
Pages (from-to)33-39
Number of pages7
JournalJournal of Chromatography A
Volume262
Issue numberC
DOIs
Publication statusPublished - 1 Jan 1983

ASJC Scopus subject areas

  • Analytical Chemistry

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