Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem, Valeska P Ting, Ulrich Hintermair, Mi Tian, Richard Telford, Saaiba Halim, Harriott Nowell, Małgorzata Hołyńska, Simon J Teat, Ian J Scowen, Sanjit Nayak

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Abstract

Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2'-diamino-4,4'-stilbenedicarboxylic acid, 4,4'-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m(2) g(-1).

Original languageEnglish
Pages (from-to)7826-7829
Number of pages4
JournalChemical Communications
Volume52
Issue number50
DOIs
Publication statusPublished - 25 Jun 2016

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Hydrogen storage
Zirconium
Metals
Acids
Hydrogen
Thermodynamic stability
Porosity
Adsorption
Water
4,4'-stilbenedicarboxylic acid

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Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity. / Naeem, Ayesha; Ting, Valeska P; Hintermair, Ulrich; Tian, Mi; Telford, Richard; Halim, Saaiba; Nowell, Harriott; Hołyńska, Małgorzata; Teat, Simon J; Scowen, Ian J; Nayak, Sanjit.

In: Chemical Communications, Vol. 52, No. 50, 25.06.2016, p. 7826-7829.

Research output: Contribution to journalArticle

Naeem, A, Ting, VP, Hintermair, U, Tian, M, Telford, R, Halim, S, Nowell, H, Hołyńska, M, Teat, SJ, Scowen, IJ & Nayak, S 2016, 'Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity', Chemical Communications, vol. 52, no. 50, pp. 7826-7829. https://doi.org/10.1039/c6cc03787a
Naeem, Ayesha ; Ting, Valeska P ; Hintermair, Ulrich ; Tian, Mi ; Telford, Richard ; Halim, Saaiba ; Nowell, Harriott ; Hołyńska, Małgorzata ; Teat, Simon J ; Scowen, Ian J ; Nayak, Sanjit. / Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity. In: Chemical Communications. 2016 ; Vol. 52, No. 50. pp. 7826-7829.
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AU - Telford, Richard

AU - Halim, Saaiba

AU - Nowell, Harriott

AU - Hołyńska, Małgorzata

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AU - Scowen, Ian J

AU - Nayak, Sanjit

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