Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem, Valeska P Ting, Ulrich Hintermair, Mi Tian, Richard Telford, Saaiba Halim, Harriott Nowell, Małgorzata Hołyńska, Simon J Teat, Ian J Scowen, Sanjit Nayak

Research output: Contribution to journalArticle

14 Citations (Scopus)
45 Downloads (Pure)

Abstract

Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2'-diamino-4,4'-stilbenedicarboxylic acid, 4,4'-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m(2) g(-1).

Original languageEnglish
Pages (from-to)7826-7829
Number of pages4
JournalChemical Communications
Volume52
Issue number50
DOIs
Publication statusPublished - 25 Jun 2016

    Fingerprint

Cite this