Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes

Ujjal Kumar Sur; Frank Marken; Barry A. Coles; Richard G. Compton; Jaïrton Dupont

doi:10.1039/b410655e

Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes

Ujjal Kumar Sur, Frank Marken, Barry A. Coles, Richard G. Compton, Jaïrton Dupont

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

Self-focusing of intense microwave radiation at the tip of a 25 μm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM⁺PF ₆^-) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)-extreme conditions sufficient for condensed phase pyrolysis processes to occur.

Original language	English
Pages (from-to)	2816-2817
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b410655e
Publication status	Published - 21 Dec 2004

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes",

abstract = "Self-focusing of intense microwave radiation at the tip of a 25 μm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM+PF 6-) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)-extreme conditions sufficient for condensed phase pyrolysis processes to occur.",

author = "Sur, \{Ujjal Kumar\} and Frank Marken and Coles, \{Barry A.\} and Compton, \{Richard G.\} and Ja{\"i}rton Dupont",

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T1 - Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes

AU - Sur, Ujjal Kumar

AU - Marken, Frank

AU - Coles, Barry A.

AU - Compton, Richard G.

AU - Dupont, Jaïrton

PY - 2004/12/21

Y1 - 2004/12/21

N2 - Self-focusing of intense microwave radiation at the tip of a 25 μm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM+PF 6-) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)-extreme conditions sufficient for condensed phase pyrolysis processes to occur.

AB - Self-focusing of intense microwave radiation at the tip of a 25 μm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM+PF 6-) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)-extreme conditions sufficient for condensed phase pyrolysis processes to occur.

UR - https://www.scopus.com/pages/publications/11244340598

U2 - 10.1039/b410655e

DO - 10.1039/b410655e

M3 - Article

AN - SCOPUS:11244340598

SN - 1359-7345

SP - 2816

EP - 2817

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes

Abstract

ASJC Scopus subject areas

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