Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity

Elena Madrid; Yuanyang Rong; Mariolino Carta; Neil B. McKeown; Richard Malpass-Evans; Gary A. Attard; Tomos J. Clarke; Stuart H. Taylor; Yi Tao Long; Frank Marken

doi:10.1002/anie.201405755

Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity

Elena Madrid
, Yuanyang Rong
, Mariolino Carta
, Neil B. McKeown
, Richard Malpass-Evans
, Gary A. Attard
, Tomos J. Clarke
, Stuart H. Taylor
, Yi Tao Long
, Frank Marken

Edinburgh Napier University
Cardiff University
East China University of Science and Technology

Research output: Contribution to journal › Article › peer-review

92 Citations (SciVal)

Abstract

A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states. Ionic flip-flop: Polymers with intrinsic microporosity introduce ionic diode and metastable switching effects as a result of their rigid backbone and molecular-structure-dependent anion versus cation conductivity.

Original language	English
Pages (from-to)	10751-10754
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	40
Early online date	11 Aug 2014
DOIs	https://doi.org/10.1002/anie.201405755
Publication status	Published - 22 Sept 2014

Keywords

diodes
fuel cells
membranes
polymers

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.201405755

Cite this

@article{a2e347aff5274adb95e79d8f436dad76,

title = "Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity",

abstract = "A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tr{\"o}ger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states. Ionic flip-flop: Polymers with intrinsic microporosity introduce ionic diode and metastable switching effects as a result of their rigid backbone and molecular-structure-dependent anion versus cation conductivity.",

keywords = "diodes, fuel cells, membranes, polymers",

author = "Elena Madrid and Yuanyang Rong and Mariolino Carta and McKeown, \{Neil B.\} and Richard Malpass-Evans and Attard, \{Gary A.\} and Clarke, \{Tomos J.\} and Taylor, \{Stuart H.\} and Long, \{Yi Tao\} and Frank Marken",

year = "2014",

month = sep,

day = "22",

doi = "10.1002/anie.201405755",

language = "English",

volume = "53",

pages = "10751--10754",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Inc.",

number = "40",

}

TY - JOUR

T1 - Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity

AU - Madrid, Elena

AU - Rong, Yuanyang

AU - Carta, Mariolino

AU - McKeown, Neil B.

AU - Malpass-Evans, Richard

AU - Attard, Gary A.

AU - Clarke, Tomos J.

AU - Taylor, Stuart H.

AU - Long, Yi Tao

AU - Marken, Frank

PY - 2014/9/22

Y1 - 2014/9/22

N2 - A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states. Ionic flip-flop: Polymers with intrinsic microporosity introduce ionic diode and metastable switching effects as a result of their rigid backbone and molecular-structure-dependent anion versus cation conductivity.

AB - A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states. Ionic flip-flop: Polymers with intrinsic microporosity introduce ionic diode and metastable switching effects as a result of their rigid backbone and molecular-structure-dependent anion versus cation conductivity.

KW - diodes

KW - fuel cells

KW - membranes

KW - polymers

UR - http://www.scopus.com/inward/record.url?scp=84923029848&partnerID=8YFLogxK

U2 - 10.1002/anie.201405755

DO - 10.1002/anie.201405755

M3 - Article

AN - SCOPUS:84923029848

SN - 1433-7851

VL - 53

SP - 10751

EP - 10754

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

ER -

Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this