Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) with organometallic monohalides; synthesis and characterisation of [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] [M′L...

John E. Davies; Martin J. Mays; Elizabeth J. Pook; Paul R. Raithby; Peter K. Tompkin

doi:10.1039/a702877f

Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L...

John E. Davies, Martin J. Mays, Elizabeth J. Pook, Paul R. Raithby, Peter K. Tompkin

University of Cambridge

Research output: Contribution to journal › Article › peer-review

12 Citations (SciVal)

Abstract

Title full: Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L_n = Mn(CO)₅, FeCp(CO)₂, MoCp(CO)₃ or WCp(CO)₃]. The anions [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) reacted with the organometallic halides [M′L_nX] [M′L_n = Mo(CO)₃Cp, X = Cl; M′L_n = W(CO)₃Cp, X = Cl; M′L_n = Fe(CO)₂Cp, X = Cl or M′L_n = Mn(CO)₅, X = Br] to afford the new complexes [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] together with [L_nM′-M′L_n], each in low yield. The crystal structure of [W₂Cp₂(CO)₄(μ-H){μ-PH[MoCp(CO) ₃]}] has been determined.

Original language	English
Pages (from-to)	3283-3286
Number of pages	4
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	18
DOIs	https://doi.org/10.1039/a702877f
Publication status	Published - 21 Sept 1997

ASJC Scopus subject areas

General Chemistry

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Davies, J. E., Mays, M. J., Pook, E. J., Raithby, P. R., & Tompkin, P. K. (1997). Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L... Journal of the Chemical Society - Dalton Transactions, (18), 3283-3286. https://doi.org/10.1039/a702877f

Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L... / Davies, John E.; Mays, Martin J.; Pook, Elizabeth J. et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 18, 21.09.1997, p. 3283-3286.

Research output: Contribution to journal › Article › peer-review

Davies, JE, Mays, MJ, Pook, EJ, Raithby, PR & Tompkin, PK 1997, 'Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L...', Journal of the Chemical Society - Dalton Transactions, no. 18, pp. 3283-3286. https://doi.org/10.1039/a702877f

Davies JE, Mays MJ, Pook EJ, Raithby PR, Tompkin PK. Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L... Journal of the Chemical Society - Dalton Transactions. 1997 Sept 21;(18):3283-3286. doi: 10.1039/a702877f

Davies, John E. ; Mays, Martin J. ; Pook, Elizabeth J. et al. / Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M₂Cp₂(CO)₄(μ-PH₂)]^- (M = Mo or W; Cp = η⁵-C₅H₅) with organometallic monohalides; synthesis and characterisation of [M₂Cp₂(CO)₄(μ-H){μ-PH(M′L _n)}] [M′L... In: Journal of the Chemical Society - Dalton Transactions. 1997 ; No. 18. pp. 3283-3286.

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title = "Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) with organometallic monohalides; synthesis and characterisation of [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] [M′L...",

abstract = "Title full: Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) with organometallic monohalides; synthesis and characterisation of [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] [M′Ln = Mn(CO)5, FeCp(CO)2, MoCp(CO)3 or WCp(CO)3]. The anions [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) reacted with the organometallic halides [M′LnX] [M′Ln = Mo(CO)3Cp, X = Cl; M′Ln = W(CO)3Cp, X = Cl; M′Ln = Fe(CO)2Cp, X = Cl or M′Ln = Mn(CO)5, X = Br] to afford the new complexes [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] together with [LnM′-M′Ln], each in low yield. The crystal structure of [W2Cp2(CO)4(μ-H){μ-PH[MoCp(CO) 3]}] has been determined.",

author = "Davies, {John E.} and Mays, {Martin J.} and Pook, {Elizabeth J.} and Raithby, {Paul R.} and Tompkin, {Peter K.}",

year = "1997",

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T1 - Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) with organometallic monohalides; synthesis and characterisation of [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] [M′L...

AU - Davies, John E.

AU - Mays, Martin J.

AU - Pook, Elizabeth J.

AU - Raithby, Paul R.

AU - Tompkin, Peter K.

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N2 - Title full: Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) with organometallic monohalides; synthesis and characterisation of [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] [M′Ln = Mn(CO)5, FeCp(CO)2, MoCp(CO)3 or WCp(CO)3]. The anions [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) reacted with the organometallic halides [M′LnX] [M′Ln = Mo(CO)3Cp, X = Cl; M′Ln = W(CO)3Cp, X = Cl; M′Ln = Fe(CO)2Cp, X = Cl or M′Ln = Mn(CO)5, X = Br] to afford the new complexes [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] together with [LnM′-M′Ln], each in low yield. The crystal structure of [W2Cp2(CO)4(μ-H){μ-PH[MoCp(CO) 3]}] has been determined.

AB - Title full: Metallation of the μ-phosphido bridging ligand in the reaction of the anion [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) with organometallic monohalides; synthesis and characterisation of [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] [M′Ln = Mn(CO)5, FeCp(CO)2, MoCp(CO)3 or WCp(CO)3]. The anions [M2Cp2(CO)4(μ-PH2)]- (M = Mo or W; Cp = η5-C5H5) reacted with the organometallic halides [M′LnX] [M′Ln = Mo(CO)3Cp, X = Cl; M′Ln = W(CO)3Cp, X = Cl; M′Ln = Fe(CO)2Cp, X = Cl or M′Ln = Mn(CO)5, X = Br] to afford the new complexes [M2Cp2(CO)4(μ-H){μ-PH(M′L n)}] together with [LnM′-M′Ln], each in low yield. The crystal structure of [W2Cp2(CO)4(μ-H){μ-PH[MoCp(CO) 3]}] has been determined.

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