Abstract
The reaction of LiBun with [(mes)2P(H)=O] affords the diorganophosphinate complex [(mes)2P(-..O)2Li·2thf] 1 and [(mes)2PLi], however, addition of [Cd{N(SiMe3)2}2] to the mixture gives the diorganophosphinite complex [{Me3-Si)2N}Cd{(mes)2P-..O} 2Li·2thf] 2; the formation of these complexes illustrates that the ligand functionality of 1 can be controlled by the character of the coordinated metal ion.
Original language | English |
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Pages (from-to) | 583-584 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 6 |
DOIs | |
Publication status | Published - 1 Jan 1997 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry