Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-..C(- ..S)]2Ba·3HMPA

F. Adele Banbury; Matthew G. Davidson; Avelino Martín; Paul R. Raithby; Ronald Snaith; Kerry L. Verhorevoort; Dominic S. Wright

doi:10.1039/C39920001152

Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-_..C(- _..S)]₂Ba·3HMPA

F. Adele Banbury
, Matthew G. Davidson
, Avelino Martín
, Paul R. Raithby
, Ronald Snaith
, Kerry L. Verhorevoort
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Solid Ba(OH)₂ suspended in toluene containing HMPA [O=P(NMe ₂)₃] reacts with the 5-aminothiatriazole, naphthyl NH·C=N·N=N·S, to give the monomeric 5- mercaptotetrazolylbarium complex, [naphthlyl N·N=N·N- _..C (-_..S)]₂Ba·3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.

Original language	English
Pages (from-to)	1152-1154
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39920001152
Publication status	Published - 31 Dec 1992

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39920001152

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Banbury, F. A., Davidson, M. G., Martín, A., Raithby, P. R., Snaith, R., Verhorevoort, K. L., & Wright, D. S. (1992). Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-_..C(- _..S)]₂Ba·3HMPA. Journal of the Chemical Society, Chemical Communications, (16), 1152-1154. https://doi.org/10.1039/C39920001152

Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-_..C(- _..S)]₂Ba·3HMPA. / Banbury, F. Adele; Davidson, Matthew G.; Martín, Avelino et al.
In: Journal of the Chemical Society, Chemical Communications, No. 16, 31.12.1992, p. 1152-1154.

Research output: Contribution to journal › Article › peer-review

Banbury, FA, Davidson, MG, Martín, A, Raithby, PR, Snaith, R, Verhorevoort, KL & Wright, DS 1992, 'Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-_..C(- _..S)]₂Ba·3HMPA', Journal of the Chemical Society, Chemical Communications, no. 16, pp. 1152-1154. https://doi.org/10.1039/C39920001152

Banbury FA, Davidson MG, Martín A, Raithby PR, Snaith R, Verhorevoort KL et al. Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-_..C(- _..S)]₂Ba·3HMPA. Journal of the Chemical Society, Chemical Communications. 1992 Dec 31;(16):1152-1154. doi: 10.1039/C39920001152

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title = "Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-..C(- ..S)]2Ba·3HMPA",

abstract = "Solid Ba(OH)2 suspended in toluene containing HMPA [O=P(NMe 2)3] reacts with the 5-aminothiatriazole, naphthyl NH·C=N·N=N·S, to give the monomeric 5- mercaptotetrazolylbarium complex, [naphthlyl N·N=N·N- ..C (-..S)]2Ba·3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.",

author = "Banbury, \{F. Adele\} and Davidson, \{Matthew G.\} and Avelino Mart{\'i}n and Raithby, \{Paul R.\} and Ronald Snaith and Verhorevoort, \{Kerry L.\} and Wright, \{Dominic S.\}",

year = "1992",

month = dec,

day = "31",

doi = "10.1039/C39920001152",

language = "English",

pages = "1152--1154",

journal = "Journal of the Chemical Society, Chemical Communications",

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number = "16",

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TY - JOUR

T1 - Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide

T2 - Synthesis and crystal structure of [naphthylN·N=·N-..C(- ..S)]2Ba·3HMPA

AU - Banbury, F. Adele

AU - Davidson, Matthew G.

AU - Martín, Avelino

AU - Raithby, Paul R.

AU - Snaith, Ronald

AU - Verhorevoort, Kerry L.

AU - Wright, Dominic S.

PY - 1992/12/31

Y1 - 1992/12/31

N2 - Solid Ba(OH)2 suspended in toluene containing HMPA [O=P(NMe 2)3] reacts with the 5-aminothiatriazole, naphthyl NH·C=N·N=N·S, to give the monomeric 5- mercaptotetrazolylbarium complex, [naphthlyl N·N=N·N- ..C (-..S)]2Ba·3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.

AB - Solid Ba(OH)2 suspended in toluene containing HMPA [O=P(NMe 2)3] reacts with the 5-aminothiatriazole, naphthyl NH·C=N·N=N·S, to give the monomeric 5- mercaptotetrazolylbarium complex, [naphthlyl N·N=N·N- ..C (-..S)]2Ba·3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.

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U2 - 10.1039/C39920001152

DO - 10.1039/C39920001152

M3 - Article

AN - SCOPUS:37049078256

SN - 0022-4936

SP - 1152

EP - 1154

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: Synthesis and crystal structure of [naphthylN·N=·N-_..C(- _..S)]₂Ba·3HMPA

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