TY - JOUR
T1 - Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide
T2 - Synthesis and crystal structure of [naphthylN·N=·N-..C(- ..S)]2Ba·3HMPA
AU - Banbury, F. Adele
AU - Davidson, Matthew G.
AU - Martín, Avelino
AU - Raithby, Paul R.
AU - Snaith, Ronald
AU - Verhorevoort, Kerry L.
AU - Wright, Dominic S.
PY - 1992/12/31
Y1 - 1992/12/31
N2 - Solid Ba(OH)2 suspended in toluene containing HMPA [O=P(NMe 2)3] reacts with the 5-aminothiatriazole, naphthyl NH·C=N·N=N·S, to give the monomeric 5- mercaptotetrazolylbarium complex, [naphthlyl N·N=N·N- ..C (-..S)]2Ba·3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.
AB - Solid Ba(OH)2 suspended in toluene containing HMPA [O=P(NMe 2)3] reacts with the 5-aminothiatriazole, naphthyl NH·C=N·N=N·S, to give the monomeric 5- mercaptotetrazolylbarium complex, [naphthlyl N·N=N·N- ..C (-..S)]2Ba·3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.
UR - http://www.scopus.com/inward/record.url?scp=37049078256&partnerID=8YFLogxK
U2 - 10.1039/C39920001152
DO - 10.1039/C39920001152
M3 - Article
AN - SCOPUS:37049078256
SN - 0022-4936
SP - 1152
EP - 1154
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 16
ER -