Mercury-bridged, nitrosyl substituted, triruthenium carbonyl clusters: Synthesis and x-ray crystal structure of [Ru3(NO)(CO)10]2Hg

M. Pilar Gómez-Sal; Brian F. G. Johnson; Jack Lewis; Paul R. Raithby; S. N.Azman B. Syed-Mustaffa

doi:10.1016/0022-328X(84)80452-0

Mercury-bridged, nitrosyl substituted, triruthenium carbonyl clusters: Synthesis and x-ray crystal structure of [Ru₃(NO)(CO)₁₀]₂Hg

M. Pilar Gómez-Sal
, Brian F. G. Johnson
, Jack Lewis
, Paul R. Raithby
, S. N.Azman B. Syed-Mustaffa

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The neutral mixed-metal cluster [Ru₃(NO)(CO)₁₀]₂Hg has been prepared by the reaction of the [Ru₃(NO)(CO)₁₀], with HgCl₂. An X-ray crystal structure shows that the mercury atom links two Ru₃ triangular units by bridging an RuRu edge of each unit. The dihedral angle between the two Ru₂Hg triangles is 27.6°. In each Ru₃ triangle a nitrosyl ligand bridges the same RuRu edge as the bridging Hg atom while the ten carbonyl groups are all terminal.

Original language	English
Pages (from-to)	C21-C24
Journal	Journal of Organometallic Chemistry
Volume	272
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(84)80452-0
Publication status	Published - 28 Aug 1984

Funding

We thank the S.E.R.C. for financial support and the Universidad Alcala de Henares (Spain) for study leave (for M.P.G.S.)

Funders
S.E.R.C.
Universidad de Alcala de Henares

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(84)80452-0

Cite this

@article{242bbd5fb2ac4471ac85525de21ec791,

title = "Mercury-bridged, nitrosyl substituted, triruthenium carbonyl clusters: Synthesis and x-ray crystal structure of [Ru3(NO)(CO)10]2Hg",

abstract = "The neutral mixed-metal cluster [Ru3(NO)(CO)10]2Hg has been prepared by the reaction of the [Ru3(NO)(CO)10], with HgCl2. An X-ray crystal structure shows that the mercury atom links two Ru3 triangular units by bridging an RuRu edge of each unit. The dihedral angle between the two Ru2Hg triangles is 27.6°. In each Ru3 triangle a nitrosyl ligand bridges the same RuRu edge as the bridging Hg atom while the ten carbonyl groups are all terminal.",

author = "\{Pilar G{\'o}mez-Sal\}, M. and Johnson, \{Brian F. G.\} and Jack Lewis and Raithby, \{Paul R.\} and Syed-Mustaffa, \{S. N.Azman B.\}",

year = "1984",

month = aug,

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doi = "10.1016/0022-328X(84)80452-0",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Mercury-bridged, nitrosyl substituted, triruthenium carbonyl clusters

T2 - Synthesis and x-ray crystal structure of [Ru3(NO)(CO)10]2Hg

AU - Pilar Gómez-Sal, M.

AU - Johnson, Brian F. G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Syed-Mustaffa, S. N.Azman B.

PY - 1984/8/28

Y1 - 1984/8/28

N2 - The neutral mixed-metal cluster [Ru3(NO)(CO)10]2Hg has been prepared by the reaction of the [Ru3(NO)(CO)10], with HgCl2. An X-ray crystal structure shows that the mercury atom links two Ru3 triangular units by bridging an RuRu edge of each unit. The dihedral angle between the two Ru2Hg triangles is 27.6°. In each Ru3 triangle a nitrosyl ligand bridges the same RuRu edge as the bridging Hg atom while the ten carbonyl groups are all terminal.

AB - The neutral mixed-metal cluster [Ru3(NO)(CO)10]2Hg has been prepared by the reaction of the [Ru3(NO)(CO)10], with HgCl2. An X-ray crystal structure shows that the mercury atom links two Ru3 triangular units by bridging an RuRu edge of each unit. The dihedral angle between the two Ru2Hg triangles is 27.6°. In each Ru3 triangle a nitrosyl ligand bridges the same RuRu edge as the bridging Hg atom while the ten carbonyl groups are all terminal.

UR - https://www.scopus.com/pages/publications/48549108760

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DO - 10.1016/0022-328X(84)80452-0

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VL - 272

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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