Measurement of solubility parameters by gas-liquid chromatrography

G. J. Price; J. E. Guillet; J. H. Purnell

doi:10.1016/S0021-9673(00)90135-3

Measurement of solubility parameters by gas-liquid chromatrography

G. J. Price, J. E. Guillet, J. H. Purnell

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Gas-liquid chromatography has been used to calculate thermodynamic data for a variety of probe molecules in three polymers at 25°C. The method of Guillet and co-workers has been applied to calculate solubility parameters, σ, and good agreement was found with literatue values. The results avoid extrapolation from higher temperatures and add further validity to the method. Discussion of the role of σ in polymer solution thermodynamics is also given.

Original language	English
Pages (from-to)	273-280
Number of pages	8
Journal	Journal of Chromatography A
Volume	369
Issue number	C
DOIs	https://doi.org/10.1016/S0021-9673(00)90135-3
Publication status	Published - 1 Jan 1986

Funding

The financial support of this researchf rom the National ResearchC ouncil of Canada and the Natural Sciencesa nd EngineeringR esearchC ouncil of Canada is gratefullya cknowledged.

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Organic Chemistry

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10.1016/S0021-9673(00)90135-3

Cite this

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abstract = "Gas-liquid chromatography has been used to calculate thermodynamic data for a variety of probe molecules in three polymers at 25°C. The method of Guillet and co-workers has been applied to calculate solubility parameters, σ, and good agreement was found with literatue values. The results avoid extrapolation from higher temperatures and add further validity to the method. Discussion of the role of σ in polymer solution thermodynamics is also given.",

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N2 - Gas-liquid chromatography has been used to calculate thermodynamic data for a variety of probe molecules in three polymers at 25°C. The method of Guillet and co-workers has been applied to calculate solubility parameters, σ, and good agreement was found with literatue values. The results avoid extrapolation from higher temperatures and add further validity to the method. Discussion of the role of σ in polymer solution thermodynamics is also given.

AB - Gas-liquid chromatography has been used to calculate thermodynamic data for a variety of probe molecules in three polymers at 25°C. The method of Guillet and co-workers has been applied to calculate solubility parameters, σ, and good agreement was found with literatue values. The results avoid extrapolation from higher temperatures and add further validity to the method. Discussion of the role of σ in polymer solution thermodynamics is also given.

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Measurement of solubility parameters by gas-liquid chromatrography

Abstract

Funding

ASJC Scopus subject areas

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