Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

Joe B. Gilroy; Sanjib K. Patra; John M. Mitchels; Mitchell A. Winnik; Ian Manners

doi:10.1002/anie.201008184

Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

Joe B. Gilroy, Sanjib K. Patra, John M. Mitchels, Mitchell A. Winnik, Ian Manners

Department of Life Sciences

Research output: Contribution to journal › Article › peer-review

101 Citations (SciVal)

Abstract

Two metals are better than one: Main-chain heterometallic block copolymers composed of iron- and cobalt-rich blocks (see picture) were synthesized through consecutive photocontrolled ring-opening polymerization (ROP) of sila[1]ferrocenophanes and dicarba[2]cobaltocenophanes followed by oxidation of the cobaltocene-containing block. The redox properties and self-assembly of the resulting block copolymers in solution were also studied.

Original language	English
Pages (from-to)	5851-5855
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	26
DOIs	https://doi.org/10.1002/anie.201008184
Publication status	Published - Jun 2011

Access to Document

10.1002/anie.201008184

Cite this

@article{146204b73a304257b585fa5c25f709e4,

title = "Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)",

abstract = "Two metals are better than one: Main-chain heterometallic block copolymers composed of iron- and cobalt-rich blocks (see picture) were synthesized through consecutive photocontrolled ring-opening polymerization (ROP) of sila[1]ferrocenophanes and dicarba[2]cobaltocenophanes followed by oxidation of the cobaltocene-containing block. The redox properties and self-assembly of the resulting block copolymers in solution were also studied.",

author = "Gilroy, \{Joe B.\} and Patra, \{Sanjib K.\} and Mitchels, \{John M.\} and Winnik, \{Mitchell A.\} and Ian Manners",

year = "2011",

month = jun,

doi = "10.1002/anie.201008184",

language = "English",

volume = "50",

pages = "5851--5855",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Inc.",

number = "26",

}

TY - JOUR

T1 - Main-chain heterobimetallic block copolymers

T2 - synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

AU - Gilroy, Joe B.

AU - Patra, Sanjib K.

AU - Mitchels, John M.

AU - Winnik, Mitchell A.

AU - Manners, Ian

PY - 2011/6

Y1 - 2011/6

N2 - Two metals are better than one: Main-chain heterometallic block copolymers composed of iron- and cobalt-rich blocks (see picture) were synthesized through consecutive photocontrolled ring-opening polymerization (ROP) of sila[1]ferrocenophanes and dicarba[2]cobaltocenophanes followed by oxidation of the cobaltocene-containing block. The redox properties and self-assembly of the resulting block copolymers in solution were also studied.

AB - Two metals are better than one: Main-chain heterometallic block copolymers composed of iron- and cobalt-rich blocks (see picture) were synthesized through consecutive photocontrolled ring-opening polymerization (ROP) of sila[1]ferrocenophanes and dicarba[2]cobaltocenophanes followed by oxidation of the cobaltocene-containing block. The redox properties and self-assembly of the resulting block copolymers in solution were also studied.

UR - https://www.scopus.com/pages/publications/79959239698

UR - http://dx.doi.org/10.1002/anie.201008184

U2 - 10.1002/anie.201008184

DO - 10.1002/anie.201008184

M3 - Article

SN - 1433-7851

VL - 50

SP - 5851

EP - 5855

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 26

ER -

Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this