Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

Joe B. Gilroy; Sanjib K. Patra; John M. Mitchels; Mitchell A. Winnik; Ian Manners

doi:10.1002/anie.201008184

Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

Joe B. Gilroy, Sanjib K. Patra, John M. Mitchels, Mitchell A. Winnik, Ian Manners

Department of Life Sciences

Research output: Contribution to journal › Article › peer-review

100 Citations (SciVal)

Abstract

Two metals are better than one: Main-chain heterometallic block copolymers composed of iron- and cobalt-rich blocks (see picture) were synthesized through consecutive photocontrolled ring-opening polymerization (ROP) of sila[1]ferrocenophanes and dicarba[2]cobaltocenophanes followed by oxidation of the cobaltocene-containing block. The redox properties and self-assembly of the resulting block copolymers in solution were also studied.

Original language	English
Pages (from-to)	5851-5855
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	26
DOIs	https://doi.org/10.1002/anie.201008184
Publication status	Published - Jun 2011

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10.1002/anie.201008184

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AU - Winnik, Mitchell A.

AU - Manners, Ian

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Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene)

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