Magnesium hydride-promoted dearomatisation of pyridine

Michael Hill; Dugald J MacDougall; Mary F Mahon

doi:10.1039/c0dt01246g

Magnesium hydride-promoted dearomatisation of pyridine

Michael Hill, Dugald J MacDougall, Mary F Mahon

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

68 Citations (SciVal)

Abstract

Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.

Original language	English
Pages (from-to)	11129-11131
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	46
DOIs	https://doi.org/10.1039/c0dt01246g
Publication status	Published - 2010

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10.1039/c0dt01246g

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title = "Magnesium hydride-promoted dearomatisation of pyridine",

abstract = "Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.",

author = "Michael Hill and MacDougall, {Dugald J} and Mahon, {Mary F}",

year = "2010",

doi = "10.1039/c0dt01246g",

language = "English",

volume = "39",

pages = "11129--11131",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Magnesium hydride-promoted dearomatisation of pyridine

AU - Hill, Michael

AU - MacDougall, Dugald J

AU - Mahon, Mary F

PY - 2010

Y1 - 2010

N2 - Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.

AB - Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.

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UR - http://dx.doi.org/10.1039/c0dt01246g

U2 - 10.1039/c0dt01246g

DO - 10.1039/c0dt01246g

M3 - Article

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VL - 39

SP - 11129

EP - 11131

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -

Magnesium hydride-promoted dearomatisation of pyridine

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Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

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Magnesium hydride-promoted dearomatisation of pyridine

Abstract

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Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

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