Projects per year
Abstract
Reaction of catalytic quantities of a -diketiminato n-butylmagnesium complex with pinacol-borane in the presence of pyridine derivatives provides facile access to borylated dihydropyridines. The reaction is applicable to a wide range of monocyclic and fused-ring pyridine derivatives and catalytic turnover is proposed to occur through a well-defined sequence of Mg-H/pyridine dearomatization and Mg-N/B-H sigma bond metathesis steps.
Original language | English |
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Pages (from-to) | 5556-5559 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 30 |
Issue number | 21 |
DOIs | |
Publication status | Published - 14 Nov 2011 |
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Dive into the research topics of 'Magnesium-catalyzed hydroboration of pyridines'. Together they form a unique fingerprint.Projects
- 1 Finished
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Group 2: Elements of 21st Century Catalysis
Hill, M. (PI)
Engineering and Physical Sciences Research Council
23/05/11 → 31/03/15
Project: Research council
Equipment
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MC2- Nuclear Magnetic Resonance (NMR)
Material and Chemical Characterisation (MC2)Facility/equipment: Technology type
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MC2- X-ray diffraction (XRD)
Material and Chemical Characterisation (MC2)Facility/equipment: Technology type