Magnesium-catalysed hydroboration of isonitriles

Catherine Weetman; Michael S. Hill; Mary F. Mahon

doi:10.1039/C5CC05708F

Magnesium-catalysed hydroboration of isonitriles

Catherine Weetman, Michael S. Hill, Mary F. Mahon

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Abstract

A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.

Original language	English
Pages (from-to)	14477-14480
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	77
Early online date	11 Aug 2015
DOIs	https://doi.org/10.1039/C5CC05708F
Publication status	Published - 4 Oct 2015

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Isonitriles_CommAccepted author manuscript, 653 KB

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@article{3917976b0dc643779a2b58d13b6adf6e,

title = "Magnesium-catalysed hydroboration of isonitriles",

abstract = "A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.",

author = "Catherine Weetman and Hill, {Michael S.} and Mahon, {Mary F.}",

year = "2015",

month = oct,

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doi = "10.1039/C5CC05708F",

language = "English",

volume = "51",

pages = "14477--14480",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "77",

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TY - JOUR

T1 - Magnesium-catalysed hydroboration of isonitriles

AU - Weetman, Catherine

AU - Hill, Michael S.

AU - Mahon, Mary F.

PY - 2015/10/4

Y1 - 2015/10/4

N2 - A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.

AB - A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.

UR - http://dx.doi.org/10.1039/C5CC05708F

U2 - 10.1039/C5CC05708F

DO - 10.1039/C5CC05708F

M3 - Article

SN - 1359-7345

VL - 51

SP - 14477

EP - 14480

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

Magnesium-catalysed hydroboration of isonitriles

Abstract

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Magnesium-catalysed hydroboration of isonitriles

Abstract

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Group 2: Elements of 21st Century Catalysis

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MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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