Magnesium-catalysed hydroboration of aldehydes and ketones

Merle Arrowsmith; T J Hadlington; Michael Hill; Gabriele Kociok-Kohn

doi:10.1039/c2cc30565h

Magnesium-catalysed hydroboration of aldehydes and ketones

Merle Arrowsmith, T J Hadlington, Michael Hill, Gabriele Kociok-Kohn

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

215 Citations (SciVal)

Abstract

The heteroleptic magnesium alkyl complex [CH{C(Me)NAr} 2Mg nBu] (Ar = 2,6- iPr 2C 6H 3) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.

Original language	English
Pages (from-to)	4567-4569
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	38
DOIs	https://doi.org/10.1039/c2cc30565h
Publication status	Published - 2012

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10.1039/c2cc30565h

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title = "Magnesium-catalysed hydroboration of aldehydes and ketones",

abstract = "The heteroleptic magnesium alkyl complex [CH{C(Me)NAr} 2Mg nBu] (Ar = 2,6- iPr 2C 6H 3) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.",

author = "Merle Arrowsmith and Hadlington, {T J} and Michael Hill and Gabriele Kociok-Kohn",

year = "2012",

doi = "10.1039/c2cc30565h",

language = "English",

volume = "48",

pages = "4567--4569",

journal = "Chemical Communications",

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AU - Arrowsmith, Merle

AU - Hadlington, T J

AU - Hill, Michael

AU - Kociok-Kohn, Gabriele

PY - 2012

Y1 - 2012

N2 - The heteroleptic magnesium alkyl complex [CH{C(Me)NAr} 2Mg nBu] (Ar = 2,6- iPr 2C 6H 3) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.

AB - The heteroleptic magnesium alkyl complex [CH{C(Me)NAr} 2Mg nBu] (Ar = 2,6- iPr 2C 6H 3) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.

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UR - http://dx.doi.org/10.1039/c2cc30565h

U2 - 10.1039/c2cc30565h

DO - 10.1039/c2cc30565h

M3 - Article

SN - 1359-7345

VL - 48

SP - 4567

EP - 4569

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Magnesium-catalysed hydroboration of aldehydes and ketones

Abstract

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Magnesium-catalysed hydroboration of aldehydes and ketones

Abstract

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Group 2: Elements of 21st Century Catalysis

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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