Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane

Matthew G. Davidson; Andrés E. Goeta; Judith A.K. Howard; Christian W. Lehmann; Garry M. McIntyre; Richard D. Price

doi:10.1016/S0022-328X(97)00551-2

Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane

Matthew G. Davidson, Andrés E. Goeta, Judith A.K. Howard, Christian W. Lehmann, Garry M. McIntyre, Richard D. Price

Research output: Contribution to journal › Article › peer-review

12 Citations (SciVal)

Abstract

The structure of imino(triphenyl)phosphorane, Ph₃PNH 1 has been determined by low-temperature X-ray and neutron diffraction. This dual study is the first such for an iminophosphorane. From the neutron diffraction data, the P-N bond length is 1.582(2) Å and the P-N-H angle is 115.0(2)°.

Original language	English
Pages (from-to)	449-452
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	550
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(97)00551-2
Publication status	Published - 15 Jan 1998

Keywords

Iminophosphorane
Phosphorus
X-ray and neutron diffraction

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(97)00551-2

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@article{34c11366beff4739a601cfa0d9eb432f,

title = "Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane",

abstract = "The structure of imino(triphenyl)phosphorane, Ph3PNH 1 has been determined by low-temperature X-ray and neutron diffraction. This dual study is the first such for an iminophosphorane. From the neutron diffraction data, the P-N bond length is 1.582(2) {\AA} and the P-N-H angle is 115.0(2)°.",

keywords = "Iminophosphorane, Phosphorus, X-ray and neutron diffraction",

author = "Davidson, \{Matthew G.\} and Goeta, \{Andr{\'e}s E.\} and Howard, \{Judith A.K.\} and Lehmann, \{Christian W.\} and McIntyre, \{Garry M.\} and Price, \{Richard D.\}",

year = "1998",

month = jan,

day = "15",

doi = "10.1016/S0022-328X(97)00551-2",

language = "English",

volume = "550",

pages = "449--452",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane

AU - Davidson, Matthew G.

AU - Goeta, Andrés E.

AU - Howard, Judith A.K.

AU - Lehmann, Christian W.

AU - McIntyre, Garry M.

AU - Price, Richard D.

PY - 1998/1/15

Y1 - 1998/1/15

N2 - The structure of imino(triphenyl)phosphorane, Ph3PNH 1 has been determined by low-temperature X-ray and neutron diffraction. This dual study is the first such for an iminophosphorane. From the neutron diffraction data, the P-N bond length is 1.582(2) Å and the P-N-H angle is 115.0(2)°.

AB - The structure of imino(triphenyl)phosphorane, Ph3PNH 1 has been determined by low-temperature X-ray and neutron diffraction. This dual study is the first such for an iminophosphorane. From the neutron diffraction data, the P-N bond length is 1.582(2) Å and the P-N-H angle is 115.0(2)°.

KW - Iminophosphorane

KW - Phosphorus

KW - X-ray and neutron diffraction

UR - https://www.scopus.com/pages/publications/0011177250

U2 - 10.1016/S0022-328X(97)00551-2

DO - 10.1016/S0022-328X(97)00551-2

M3 - Article

AN - SCOPUS:0011177250

SN - 0022-328X

VL - 550

SP - 449

EP - 452

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane

Abstract

Keywords

ASJC Scopus subject areas

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