Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C5H5)2Pb·tmeda] and [(η -C5H5)2Pb·4,4′-Me2 bipy] (tmeda = Me2NCH2CH2NMe2, 4,4′-Me2bipy = 4,4′-dimethylbipyridine)

Michael A. Beswick; Natalie L. Cromhout; Christopher N. Harmer; Paul R. Raithby; Christopher A. Russell; Justin S.B. Smith; Alexander Steiner; Dominic S. Wright

doi:10.1039/CC9960001977

Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C₅H₅)₂Pb·tmeda] and [(η -C₅H₅)₂Pb·4,4′-Me₂ bipy] (tmeda = Me₂NCH₂CH₂NMe₂, 4,4′-Me₂bipy = 4,4′-dimethylbipyridine)

Michael A. Beswick
, Natalie L. Cromhout
, Christopher N. Harmer
, Paul R. Raithby
, Christopher A. Russell
, Justin S.B. Smith
, Alexander Steiner
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

22 Citations (SciVal)

Abstract

The first Lewis-base adducts of a neutral p-block group metallocene, [(η-C5H₅)₂Pb-tmeda] 1 and [η-C₅H₅)₂Pb·4,4′-Me ₂bipy] 2, result from the addition of tmeda and 4,4′-Me₂bipy to [Pb(η-C₅H₅)₂] (1:1 equiv.); X-ray and solution studies reveal that the Lewis bases are only loosely associated to the Pb^II centres in these complexes.

Original language	English
Pages (from-to)	1977-1978
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/CC9960001977
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/CC9960001977

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Beswick, M. A., Cromhout, N. L., Harmer, C. N., Raithby, P. R., Russell, C. A., Smith, J. S. B., Steiner, A., & Wright, D. S. (1996). Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C₅H₅)₂Pb·tmeda] and [(η -C₅H₅)₂Pb·4,4′-Me₂ bipy] (tmeda = Me₂NCH₂CH₂NMe₂, 4,4′-Me₂bipy = 4,4′-dimethylbipyridine). Chemical Communications, (16), 1977-1978. https://doi.org/10.1039/CC9960001977

Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C₅H₅)₂Pb·tmeda] and [(η -C₅H₅)₂Pb·4,4′-Me₂ bipy] (tmeda = Me₂NCH₂CH₂NMe₂, 4,4′-Me₂bipy = 4,4′-dimethylbipyridine). / Beswick, Michael A.; Cromhout, Natalie L.; Harmer, Christopher N. et al.
In: Chemical Communications, No. 16, 01.01.1996, p. 1977-1978.

Research output: Contribution to journal › Article › peer-review

Beswick, MA, Cromhout, NL, Harmer, CN, Raithby, PR, Russell, CA, Smith, JSB, Steiner, A & Wright, DS 1996, 'Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C₅H₅)₂Pb·tmeda] and [(η -C₅H₅)₂Pb·4,4′-Me₂ bipy] (tmeda = Me₂NCH₂CH₂NMe₂, 4,4′-Me₂bipy = 4,4′-dimethylbipyridine)', Chemical Communications, no. 16, pp. 1977-1978. https://doi.org/10.1039/CC9960001977

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title = "Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C5H5)2Pb·tmeda] and [(η -C5H5)2Pb·4,4′-Me2 bipy] (tmeda = Me2NCH2CH2NMe2, 4,4′-Me2bipy = 4,4′-dimethylbipyridine)",

abstract = "The first Lewis-base adducts of a neutral p-block group metallocene, [(η-C5H5)2Pb-tmeda] 1 and [η-C5H5)2Pb·4,4′-Me 2bipy] 2, result from the addition of tmeda and 4,4′-Me2bipy to [Pb(η-C5H5)2] (1:1 equiv.); X-ray and solution studies reveal that the Lewis bases are only loosely associated to the PbII centres in these complexes.",

author = "Beswick, \{Michael A.\} and Cromhout, \{Natalie L.\} and Harmer, \{Christopher N.\} and Raithby, \{Paul R.\} and Russell, \{Christopher A.\} and Smith, \{Justin S.B.\} and Alexander Steiner and Wright, \{Dominic S.\}",

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AU - Beswick, Michael A.

AU - Cromhout, Natalie L.

AU - Harmer, Christopher N.

AU - Raithby, Paul R.

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AB - The first Lewis-base adducts of a neutral p-block group metallocene, [(η-C5H5)2Pb-tmeda] 1 and [η-C5H5)2Pb·4,4′-Me 2bipy] 2, result from the addition of tmeda and 4,4′-Me2bipy to [Pb(η-C5H5)2] (1:1 equiv.); X-ray and solution studies reveal that the Lewis bases are only loosely associated to the PbII centres in these complexes.

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DO - 10.1039/CC9960001977

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Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C₅H₅)₂Pb·tmeda] and [(η -C₅H₅)₂Pb·4,4′-Me₂ bipy] (tmeda = Me₂NCH₂CH₂NMe₂, 4,4′-Me₂bipy = 4,4′-dimethylbipyridine)

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