Lithium and potassium aminoalkoxides

S.D. Cosham, A.L. Johnson, Laura Jordan, M.F. Mahon, K.C. Molloy

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Abstract

The structures of the Group 1 metal aminoalkoxides Li[OCH(CH CNMe)] (1) and K[OCH(CHCNMe )]·H OCH(CHCNMe) (2) have been determined. 1 is a hexameric drum in which two Li O rings are joined co-facially, whereas 2 is tetrameric and adopts a K Oladder structure, novel for homoleptic potassium alkoxides.
Original languageEnglish
Pages (from-to)153-157
Number of pages5
JournalMain Group Metal Chemistry
Volume35
Issue number5-6
DOIs
Publication statusPublished - Sept 2012

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