Lithiation of a Simple Amine with a Large Excess of n-Butyllithium: The Remarkable Product (Ph2NLi)·[Ph(C6H4Li)NLi] 2· (nBuLi)2·(Et2O)4

Robert P. Davies; Paul R. Raithby; Ronald Snaith

doi:10.1002/anie.199712151

Lithiation of a Simple Amine with a Large Excess of n-Butyllithium: The Remarkable Product (Ph₂NLi)·[Ph(C₆H₄Li)NLi] ₂· (nBuLi)₂·(Et₂O)₄

Robert P. Davies, Paul R. Raithby, Ronald Snaith

University of Cambridge

Research output: Contribution to journal › Article › peer-review

38 Citations (SciVal)

Abstract

What lithiates what? In a reaction between Ph2NH and excess nBuLi the aggregate 1 comprising nBuLi, monolitiated amine, and doubly lithiated amine units forms. The structure (see picture) raises interesting questions about lithiation reaction mechanisms.

Original language	English
Pages (from-to)	1215-1217
Number of pages	3
Journal	Angewandte Chemie (International Edition in English)
Volume	36
Issue number	11
DOIs	https://doi.org/10.1002/anie.199712151
Publication status	Published - 16 Jun 1997

Keywords

Amides
Lithiation
Lithium
Reaction mechanisms
Solid-state structures

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.199712151

Cite this

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KW - Solid-state structures

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