Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

Andrew M Collins; John D Watkins; Najoua Katif; Y J Huang; Y B Jiang; Tony D James; Steven D Bull; Frank Marken

doi:10.1039/c1cc15211d

Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

Andrew M Collins
, John D Watkins
, Najoua Katif
, Y J Huang
, Y B Jiang
, Tony D James
, Steven D Bull
, Frank Marken

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (SciVal)

Abstract

Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

Original language	English
Pages (from-to)	12002-12004
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	43
DOIs	https://doi.org/10.1039/c1cc15211d
Publication status	Published - 2011

Access to Document

10.1039/c1cc15211d

Cite this

@article{0c2dd6d3935941d1be28f5657a296c8d,

title = "Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids",

abstract = "Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).",

author = "Collins, \{Andrew M\} and Watkins, \{John D\} and Najoua Katif and Huang, \{Y J\} and Jiang, \{Y B\} and James, \{Tony D\} and Bull, \{Steven D\} and Frank Marken",

year = "2011",

doi = "10.1039/c1cc15211d",

language = "English",

volume = "47",

pages = "12002--12004",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

AU - Collins, Andrew M

AU - Watkins, John D

AU - Katif, Najoua

AU - Huang, Y J

AU - Jiang, Y B

AU - James, Tony D

AU - Bull, Steven D

AU - Marken, Frank

PY - 2011

Y1 - 2011

N2 - Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

AB - Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

UR - https://www.scopus.com/pages/publications/80054895117

UR - http://dx.doi.org/10.1039/c1cc15211d

U2 - 10.1039/c1cc15211d

DO - 10.1039/c1cc15211d

M3 - Article

SN - 1359-7345

VL - 47

SP - 12002

EP - 12004

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

Abstract

Access to Document

Other files and links

Fingerprint

Microphase Photo-Electrochemistry: Light-Driven Liquid-Liquid Ion Transfer Processes and Two-Phase Micro-Photovoltaic Systems

Cite this

Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

Abstract

Access to Document

Other files and links

Fingerprint

Projects

Microphase Photo-Electrochemistry: Light-Driven Liquid-Liquid Ion Transfer Processes and Two-Phase Micro-Photovoltaic Systems

Cite this