Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

Andrew M Collins; John D Watkins; Najoua Katif; Y J Huang; Y B Jiang; Tony D James; Steven D Bull; Frank Marken

doi:10.1039/c1cc15211d

Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

Andrew M Collins, John D Watkins, Najoua Katif, Y J Huang, Y B Jiang, Tony D James, Steven D Bull, Frank Marken

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (SciVal)

Abstract

Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

Original language	English
Pages (from-to)	12002-12004
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	43
DOIs	https://doi.org/10.1039/c1cc15211d
Publication status	Published - 2011

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10.1039/c1cc15211d

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title = "Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids",

abstract = "Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).",

author = "Collins, {Andrew M} and Watkins, {John D} and Najoua Katif and Huang, {Y J} and Jiang, {Y B} and James, {Tony D} and Bull, {Steven D} and Frank Marken",

year = "2011",

doi = "10.1039/c1cc15211d",

language = "English",

volume = "47",

pages = "12002--12004",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "43",

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TY - JOUR

T1 - Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

AU - Collins, Andrew M

AU - Watkins, John D

AU - Katif, Najoua

AU - Huang, Y J

AU - Jiang, Y B

AU - James, Tony D

AU - Bull, Steven D

AU - Marken, Frank

PY - 2011

Y1 - 2011

N2 - Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

AB - Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

UR - http://www.scopus.com/inward/record.url?scp=80054895117&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1039/c1cc15211d

U2 - 10.1039/c1cc15211d

DO - 10.1039/c1cc15211d

M3 - Article

SN - 1359-7345

VL - 47

SP - 12002

EP - 12004

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

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Microphase Photo-Electrochemistry: Light-Driven Liquid-Liquid Ion Transfer Processes and Two-Phase Micro-Photovoltaic Systems

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Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

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Microphase Photo-Electrochemistry: Light-Driven Liquid-Liquid Ion Transfer Processes and Two-Phase Micro-Photovoltaic Systems

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