Ligand transfer from a tris(imino)stannate anion; Syntheses and structures of [{Cu[μ-N=C(But)Ph]}4]·thf(thf = tetrahydrofuran) and [{Cu[μ- N=C(But)Ph]}4(PPh 3)2]·6thf

Maxwell K. Davies; Paul R. Raithby; Moira Ann Rennie; Alexander Steiner; Dominic S. Wright

doi:10.1039/DT9950002707

Ligand transfer from a tris(imino)stannate anion; Syntheses and structures of [{Cu[μ-N=C(Bu^t)Ph]}₄]·thf(thf = tetrahydrofuran) and [{Cu[μ- N=C(Bu^t)Ph]}₄(PPh ₃)₂]·6thf

Maxwell K. Davies, Paul R. Raithby, Moira Ann Rennie, Alexander Steiner, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The group 11 metal imino complexes [{Cu[μ-N=C(Bu^t)Ph]} ₄]·thf 2 (thf = tetrahydrofuran) and [{Cu[μ-N=C(Bu ^t)Ph]}₄(PPh₃)₂]·6thf 3 have been prepared by the unusual ligand-transfer reactions of the tris(imino)stannate complex Sn[μ-N=C(Bu^t)Ph]₃Li· thf with CuCl; both complexes have been shown by crystallography to contain planar Cu₄ cores.

Original language	English
Pages (from-to)	2707-2709
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Volume	1995
Issue number	16
DOIs	https://doi.org/10.1039/DT9950002707
Publication status	Published - 31 Dec 1995

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General Chemistry

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Ligand transfer from a tris(imino)stannate anion; Syntheses and structures of [{Cu[μ-N=C(Bu^t)Ph]}₄]·thf(thf = tetrahydrofuran) and [{Cu[μ- N=C(Bu^t)Ph]}₄(PPh ₃)₂]·6thf. / Davies, Maxwell K.; Raithby, Paul R.; Rennie, Moira Ann et al.
In: Journal of the Chemical Society, Dalton Transactions, Vol. 1995, No. 16, 31.12.1995, p. 2707-2709.

Research output: Contribution to journal › Article › peer-review

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abstract = "The group 11 metal imino complexes [{Cu[μ-N=C(But)Ph]} 4]·thf 2 (thf = tetrahydrofuran) and [{Cu[μ-N=C(Bu t)Ph]}4(PPh3)2]·6thf 3 have been prepared by the unusual ligand-transfer reactions of the tris(imino)stannate complex Sn[μ-N=C(But)Ph]3Li· thf with CuCl; both complexes have been shown by crystallography to contain planar Cu4 cores.",

author = "Davies, {Maxwell K.} and Raithby, {Paul R.} and Rennie, {Moira Ann} and Alexander Steiner and Wright, {Dominic S.}",

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AU - Davies, Maxwell K.

AU - Raithby, Paul R.

AU - Rennie, Moira Ann

AU - Steiner, Alexander

AU - Wright, Dominic S.

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AB - The group 11 metal imino complexes [{Cu[μ-N=C(But)Ph]} 4]·thf 2 (thf = tetrahydrofuran) and [{Cu[μ-N=C(Bu t)Ph]}4(PPh3)2]·6thf 3 have been prepared by the unusual ligand-transfer reactions of the tris(imino)stannate complex Sn[μ-N=C(But)Ph]3Li· thf with CuCl; both complexes have been shown by crystallography to contain planar Cu4 cores.

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Ligand transfer from a tris(imino)stannate anion; Syntheses and structures of [{Cu[μ-N=C(Bu^t)Ph]}₄]·thf(thf = tetrahydrofuran) and [{Cu[μ- N=C(Bu^t)Ph]}₄(PPh ₃)₂]·6thf

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