Layered LaSrGa(3)O7-Based Oxide-Ion Conductors: Cooperative Transport Mechanisms and Flexible Structures

C Tealdi, P Mustarelli, M Saiful Islam

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Novel melilite-type gallium-oxides are attracting attention as promising new oxide-ion conductors with potential use in clean energy devices such as solid oxide fuel cells. Here, an atomic-scale investigation of the LaSrGa3O7-based system using advanced simulation techniques provides valuable insights into the defect chemistry and oxide ion conduction mechanisms, and includes comparison with the available experimental data. The simulation model reproduces the observed complex structure composed of layers of corner-sharing GaO4 tetrahedra. A major finding is the first indication that oxide-ion conduction in La(1.5)4Sr(0.46)Ga(3)O(7.27) occurs through an interstitialcy or cooperative-type mechanism involving the concerted knock-on motion of interstitial and lattice oxide ions. A key feature for the transport mechanism and high ionic conductivity is the intrinsic flexibility of the structure, which allows considerable local relaxation and changes in Ga coordination.
Original languageEnglish
Pages (from-to)3874-3880
Number of pages7
JournalAdvanced Functional Materials
Volume20
Issue number22
DOIs
Publication statusPublished - 23 Nov 2010

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Flexible structures
Oxides
Ions
Ionic conductivity
Solid oxide fuel cells (SOFC)
Gallium
Defects

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Layered LaSrGa(3)O7-Based Oxide-Ion Conductors: Cooperative Transport Mechanisms and Flexible Structures. / Tealdi, C; Mustarelli, P; Islam, M Saiful.

In: Advanced Functional Materials, Vol. 20, No. 22, 23.11.2010, p. 3874-3880.

Research output: Contribution to journalArticle

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