Isolation of the elusive [Ru(bipy)3]+: a key intermediate in photoredox catalysis

Samuel Horsewill; Chengyang  Cao; Noah Dabney; Eric S. Yang; Stephen Faulkner; Daniel Scott

doi:10.1039/D3CC04375D

Isolation of the elusive [Ru(bipy)3]+: a key intermediate in photoredox catalysis

Samuel Horsewill, Chengyang Cao, Noah Dabney, Eric S. Yang, Stephen Faulkner, Daniel Scott

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Abstract

Photoredox catalysis has flourished in recent years, but due to its widespread utility applications have grown faster than mechanistic understanding. In this report we help to address this deficit by isolating and characterising one of the intermediates of the iconic photocatalyst [Ru(bipy)3]2+, and testing its initial photoreactivity towards common substrates.

Original language	English
Pages (from-to)	14665-14668
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	59
Issue number	99
Early online date	15 Nov 2023
DOIs	https://doi.org/10.1039/D3CC04375D
Publication status	Published - 25 Dec 2023

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10.1039/D3CC04375DLicence: CC BY

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abstract = "Photoredox catalysis has flourished in recent years, but due to its widespread utility applications have grown faster than mechanistic understanding. In this report we help to address this deficit by isolating and characterising one of the intermediates of the iconic photocatalyst [Ru(bipy)3]2+, and testing its initial photoreactivity towards common substrates.",

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AU - Faulkner, Stephen

AU - Scott, Daniel

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AB - Photoredox catalysis has flourished in recent years, but due to its widespread utility applications have grown faster than mechanistic understanding. In this report we help to address this deficit by isolating and characterising one of the intermediates of the iconic photocatalyst [Ru(bipy)3]2+, and testing its initial photoreactivity towards common substrates.

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Isolation of the elusive [Ru(bipy)3]+: a key intermediate in photoredox catalysis

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Shining a New Light on Photoredox Catalysis and Small Molecule Activation

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Isolation of the elusive [Ru(bipy)3]+: a key intermediate in photoredox catalysis

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Shining a New Light on Photoredox Catalysis and Small Molecule Activation

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