Isolation of [Ru(IPr)2(CO)H]+ (IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene) and reactivity towards E-H (E = H, B) bonds

Ian M. Riddlestone; David McKay; Matthias J. Gutmann; Stuart A. MacGregor; Mary F. Mahon; Hazel A. Sparkes; Michael K. Whittlesey

doi:10.1021/acs.organomet.6b00173

Isolation of [Ru(IPr)₂(CO)H]⁺ (IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene) and reactivity towards E-H (E = H, B) bonds

Ian M. Riddlestone
, David McKay
, Matthias J. Gutmann
, Stuart A. MacGregor
, Mary F. Mahon
, Hazel A. Sparkes
, Michael K. Whittlesey

Department of Chemistry

Heriot-Watt University
Rutherford Appleton Laboratory
University of Bristol

Research output: Contribution to journal › Article › peer-review

18 Citations (SciVal)

277 Downloads (Pure)

Original language	English
Pages (from-to)	1301-1312
Journal	Organometallics
Volume	35
Issue number	9
Early online date	26 Apr 2016
DOIs	https://doi.org/10.1021/acs.organomet.6b00173
Publication status	Published - 9 May 2016

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10.1021/acs.organomet.6b00173

Whittlesey_PURE_Organometallics
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see DOI: 10.1021/acs.organomet.6b00173.
Accepted author manuscript, 1.61 MB

http://dx.doi.org/10.1021/acs.organomet.6b00173

Cite this

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title = "Isolation of [Ru(IPr)2(CO)H]+ (IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene) and reactivity towards E-H (E = H, B) bonds",

author = "Riddlestone, \{Ian M.\} and David McKay and Gutmann, \{Matthias J.\} and MacGregor, \{Stuart A.\} and Mahon, \{Mary F.\} and Sparkes, \{Hazel A.\} and Whittlesey, \{Michael K.\}",

year = "2016",

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AU - Riddlestone, Ian M.

AU - McKay, David

AU - Gutmann, Matthias J.

AU - MacGregor, Stuart A.

AU - Mahon, Mary F.

AU - Sparkes, Hazel A.

AU - Whittlesey, Michael K.

PY - 2016/5/9

Y1 - 2016/5/9

UR - http://dx.doi.org/10.1021/acs.organomet.6b00173

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DO - 10.1021/acs.organomet.6b00173

M3 - Article

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VL - 35

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EP - 1312

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Isolation of [Ru(IPr)₂(CO)H]⁺ (IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene) and reactivity towards E-H (E = H, B) bonds

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Other files and links

Catalytic Functionalisation of Aromatic Fluorocarbons

Dual source (Cu and Mo) Single Crystal Diffractometer (SuperNova)

MC2-Mass Spectrometry (MS)

MC2- Nuclear Magnetic Resonance (NMR)

Cite this

Isolation of [Ru(IPr)2(CO)H]+ (IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene) and reactivity towards E-H (E = H, B) bonds

Access to Document

Other files and links

Projects

Catalytic Functionalisation of Aromatic Fluorocarbons

Equipment

Dual source (Cu and Mo) Single Crystal Diffractometer (SuperNova)

MC2-Mass Spectrometry (MS)

MC2- Nuclear Magnetic Resonance (NMR)

Cite this

Isolation of [Ru(IPr)₂(CO)H]⁺ (IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene) and reactivity towards E-H (E = H, B) bonds