TY - JOUR
T1 - Isolation of intermediates in the acid hydrolysis of [Pt(PPh 3)2(O2)]; the X-ray structure of [Pt 2(O2)(OH)(PPh3)4][ClO 4]·2C6H6
AU - Bhaduri, Sumit
AU - Raithby, Paul R.
AU - Zuccaro, Camilo I.
AU - Hursthouse, Michael B.
AU - Casella, Luigi
AU - Ugo, Renato
PY - 1978/12/31
Y1 - 1978/12/31
N2 - The hydrolysis of [Pt(PPh3)2(O2)] with non-co-ordinating acids leads to the formation of [Pt2(O 2)(OH)(PPh3)4][X] (1) (X = ClO4, PF6, BF4, NO3), and then [Pt 2(OH)2(PPh3)4][X]2 (2), with a stepwise loss of H2O2; the structure of (1) has been confirmed by an X-ray analysis.
AB - The hydrolysis of [Pt(PPh3)2(O2)] with non-co-ordinating acids leads to the formation of [Pt2(O 2)(OH)(PPh3)4][X] (1) (X = ClO4, PF6, BF4, NO3), and then [Pt 2(OH)2(PPh3)4][X]2 (2), with a stepwise loss of H2O2; the structure of (1) has been confirmed by an X-ray analysis.
UR - http://www.scopus.com/inward/record.url?scp=37049100395&partnerID=8YFLogxK
U2 - 10.1039/C39780000991
DO - 10.1039/C39780000991
M3 - Article
AN - SCOPUS:37049100395
SN - 0022-4936
SP - 991
EP - 992
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 22
ER -