Isolation of intermediates in the acid hydrolysis of [Pt(PPh 3)2(O2)]; the X-ray structure of [Pt 2(O2)(OH)(PPh3)4][ClO 4]·2C6H6

Sumit Bhaduri; Paul R. Raithby; Camilo I. Zuccaro; Michael B. Hursthouse; Luigi Casella; Renato Ugo

doi:10.1039/C39780000991

Isolation of intermediates in the acid hydrolysis of [Pt(PPh ₃)₂(O₂)]; the X-ray structure of [Pt ₂(O₂)(OH)(PPh₃)₄][ClO ₄]·2C₆H₆

Sumit Bhaduri
, Paul R. Raithby
, Camilo I. Zuccaro
, Michael B. Hursthouse
, Luigi Casella
, Renato Ugo

University Che
Queen Mary University, London
Consiglio Nazionale delle Ricerche

Research output: Contribution to journal › Article › peer-review

Abstract

The hydrolysis of [Pt(PPh₃)₂(O₂)] with non-co-ordinating acids leads to the formation of [Pt₂(O ₂)(OH)(PPh₃)₄][X] (1) (X = ClO₄, PF₆, BF₄, NO₃), and then [Pt ₂(OH)₂(PPh₃)₄][X]₂ (2), with a stepwise loss of H₂O₂; the structure of (1) has been confirmed by an X-ray analysis.

Original language	English
Pages (from-to)	991-992
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39780000991
Publication status	Published - 31 Dec 1978

ASJC Scopus subject areas

Molecular Medicine

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@article{cabeeefc4d304dc28c3e866be1552148,

title = "Isolation of intermediates in the acid hydrolysis of [Pt(PPh 3)2(O2)]; the X-ray structure of [Pt 2(O2)(OH)(PPh3)4][ClO 4]·2C6H6",

abstract = "The hydrolysis of [Pt(PPh3)2(O2)] with non-co-ordinating acids leads to the formation of [Pt2(O 2)(OH)(PPh3)4][X] (1) (X = ClO4, PF6, BF4, NO3), and then [Pt 2(OH)2(PPh3)4][X]2 (2), with a stepwise loss of H2O2; the structure of (1) has been confirmed by an X-ray analysis.",

author = "Sumit Bhaduri and Raithby, \{Paul R.\} and Zuccaro, \{Camilo I.\} and Hursthouse, \{Michael B.\} and Luigi Casella and Renato Ugo",

year = "1978",

month = dec,

day = "31",

doi = "10.1039/C39780000991",

language = "English",

pages = "991--992",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "22",

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TY - JOUR

T1 - Isolation of intermediates in the acid hydrolysis of [Pt(PPh 3)2(O2)]; the X-ray structure of [Pt 2(O2)(OH)(PPh3)4][ClO 4]·2C6H6

AU - Bhaduri, Sumit

AU - Raithby, Paul R.

AU - Zuccaro, Camilo I.

AU - Hursthouse, Michael B.

AU - Casella, Luigi

AU - Ugo, Renato

PY - 1978/12/31

Y1 - 1978/12/31

N2 - The hydrolysis of [Pt(PPh3)2(O2)] with non-co-ordinating acids leads to the formation of [Pt2(O 2)(OH)(PPh3)4][X] (1) (X = ClO4, PF6, BF4, NO3), and then [Pt 2(OH)2(PPh3)4][X]2 (2), with a stepwise loss of H2O2; the structure of (1) has been confirmed by an X-ray analysis.

AB - The hydrolysis of [Pt(PPh3)2(O2)] with non-co-ordinating acids leads to the formation of [Pt2(O 2)(OH)(PPh3)4][X] (1) (X = ClO4, PF6, BF4, NO3), and then [Pt 2(OH)2(PPh3)4][X]2 (2), with a stepwise loss of H2O2; the structure of (1) has been confirmed by an X-ray analysis.

UR - https://www.scopus.com/pages/publications/37049100395

U2 - 10.1039/C39780000991

DO - 10.1039/C39780000991

M3 - Article

AN - SCOPUS:37049100395

SN - 0022-4936

SP - 991

EP - 992

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

Isolation of intermediates in the acid hydrolysis of [Pt(PPh ₃)₂(O₂)]; the X-ray structure of [Pt ₂(O₂)(OH)(PPh₃)₄][ClO ₄]·2C₆H₆

Abstract

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