Isolation, characterisation, and crystal and molecular structure of [Os6AuC(CO)20(μ-OMe)]

Caroline M. Hay; Brian F.G. Johnson; Jack Lewis; Neville D. Prior; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(91)86216-D

Isolation, characterisation, and crystal and molecular structure of [Os₆AuC(CO)₂₀(μ-OMe)]

Caroline M. Hay, Brian F.G. Johnson, Jack Lewis, Neville D. Prior, Paul R. Raithby, Wing Tak Wong

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Treatment of [Os₃(CO)₁₀(μ-AuPEt₃)(μ-COMe)] with [Os₃(CO)₁₀(NCMe)₂] in refluxing toluene affords the new carbido compound [Os₆AuC(CO)₂₀(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os₂ fragment and an Os₄ carbido fragment are linked together by a gold atom.

Original language	English
Pages (from-to)	C20-C22
Journal	Journal of Organometallic Chemistry
Volume	401
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(91)86216-D
Publication status	Published - 8 Jan 1991

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(91)86216-D

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title = "Isolation, characterisation, and crystal and molecular structure of [Os6AuC(CO)20(μ-OMe)]",

abstract = "Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2 fragment and an Os4 carbido fragment are linked together by a gold atom.",

author = "Hay, {Caroline M.} and Johnson, {Brian F.G.} and Jack Lewis and Prior, {Neville D.} and Raithby, {Paul R.} and {Tak Wong}, Wing",

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AU - Hay, Caroline M.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Prior, Neville D.

AU - Raithby, Paul R.

AU - Tak Wong, Wing

PY - 1991/1/8

Y1 - 1991/1/8

N2 - Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2 fragment and an Os4 carbido fragment are linked together by a gold atom.

AB - Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2 fragment and an Os4 carbido fragment are linked together by a gold atom.

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U2 - 10.1016/0022-328X(91)86216-D

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M3 - Article

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IS - 1-2

ER -

Isolation, characterisation, and crystal and molecular structure of [Os₆AuC(CO)₂₀(μ-OMe)]

Abstract

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