Isolation and X-ray structure determination of [Os4(CO) 12(C9H6)], an indyne'butterfly' cluster

Hong Chen; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1039/C39900000373

Isolation and X-ray structure determination of [Os₄(CO) ₁₂(C₉H₆)], an indyne'butterfly' cluster

Hong Chen, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster [Os₄(CO)₁₂(C₉H₆)] (1) has been isolated from the reaction of [Os₃(CO)₁₂] with indene in nonane under reflux; X-ray analysis has shown that (1) has a 'butterfly' metal framework while the indyne group interacts with the metal atoms via two σ-bonds and two π-bonds.

Original language	English
Pages (from-to)	373-374
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39900000373
Publication status	Published - 31 Dec 1990

ASJC Scopus subject areas

Molecular Medicine

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abstract = "The cluster [Os4(CO)12(C9H6)] (1) has been isolated from the reaction of [Os3(CO)12] with indene in nonane under reflux; X-ray analysis has shown that (1) has a 'butterfly' metal framework while the indyne group interacts with the metal atoms via two σ-bonds and two π-bonds.",

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AB - The cluster [Os4(CO)12(C9H6)] (1) has been isolated from the reaction of [Os3(CO)12] with indene in nonane under reflux; X-ray analysis has shown that (1) has a 'butterfly' metal framework while the indyne group interacts with the metal atoms via two σ-bonds and two π-bonds.

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Isolation and X-ray structure determination of [Os₄(CO) ₁₂(C₉H₆)], an indyne'butterfly' cluster

Abstract

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