Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands

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Abstract

Reaction of Zr((OPr)-Pr-i)(4) or Sn[N(SiMe3)(2)](2) with the tris-phenol amine ligand H3L(Me/Me) results in the formation of zirconium or tin complexes containing the new C-3-symmetric zwitterionic ammonium- trisphenolate ligand HL2-, while increasing the steric bulk of the ligand results in the isolation of a zirconium complex containing the known trianionic ligand L3-.
Original languageEnglish
Pages (from-to)1832-1833
Number of pages2
JournalChemical Communications
Volume2003
Issue number15
DOIs
Publication statusPublished - 19 Jun 2003

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