Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands

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Abstract

Reaction of Zr((OPr)-Pr-i)(4) or Sn[N(SiMe3)(2)](2) with the tris-phenol amine ligand H3L(Me/Me) results in the formation of zirconium or tin complexes containing the new C-3-symmetric zwitterionic ammonium- trisphenolate ligand HL2-, while increasing the steric bulk of the ligand results in the isolation of a zirconium complex containing the known trianionic ligand L3-.
Original languageEnglish
Pages (from-to)1832-1833
Number of pages2
JournalChemical Communications
Volume2003
Issue number15
DOIs
Publication statusPublished - 19 Jun 2003

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Coordination Complexes
Metal complexes
Hydrogen
Ligands
Zirconium
Tin
Phenol
Ammonium Compounds
Phenols
Amines

Cite this

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title = "Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands",
abstract = "Reaction of Zr((OPr)-Pr-i)(4) or Sn[N(SiMe3)(2)](2) with the tris-phenol amine ligand H3L(Me/Me) results in the formation of zirconium or tin complexes containing the new C-3-symmetric zwitterionic ammonium- trisphenolate ligand HL2-, while increasing the steric bulk of the ligand results in the isolation of a zirconium complex containing the known trianionic ligand L3-.",
author = "Davidson, {Matthew G.} and Doherty, {Cheryl L.} and Johnson, {Andrew L.} and Mahon, {Mary F.}",
year = "2003",
month = "6",
day = "19",
doi = "10.1039/b303618a",
language = "English",
volume = "2003",
pages = "1832--1833",
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publisher = "Royal Society of Chemistry",
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T1 - Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands

AU - Davidson, Matthew G.

AU - Doherty, Cheryl L.

AU - Johnson, Andrew L.

AU - Mahon, Mary F.

PY - 2003/6/19

Y1 - 2003/6/19

N2 - Reaction of Zr((OPr)-Pr-i)(4) or Sn[N(SiMe3)(2)](2) with the tris-phenol amine ligand H3L(Me/Me) results in the formation of zirconium or tin complexes containing the new C-3-symmetric zwitterionic ammonium- trisphenolate ligand HL2-, while increasing the steric bulk of the ligand results in the isolation of a zirconium complex containing the known trianionic ligand L3-.

AB - Reaction of Zr((OPr)-Pr-i)(4) or Sn[N(SiMe3)(2)](2) with the tris-phenol amine ligand H3L(Me/Me) results in the formation of zirconium or tin complexes containing the new C-3-symmetric zwitterionic ammonium- trisphenolate ligand HL2-, while increasing the steric bulk of the ligand results in the isolation of a zirconium complex containing the known trianionic ligand L3-.

UR - http://dx.doi.org/10.1039/b303618a

U2 - 10.1039/b303618a

DO - 10.1039/b303618a

M3 - Article

VL - 2003

SP - 1832

EP - 1833

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

SN - 1359-7345

IS - 15

ER -