Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters

Monika Ali Khan; M F Mahon; A J W Stewart; S E Lewis

doi:10.1021/om9009069

Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters

Monika Ali Khan, M F Mahon, A J W Stewart, S E Lewis

Department of Chemistry

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Abstract

Tricarbonyliron(0) complexes of novel cyclohexadiene ligands possessing quaternary centers have been synthesized and characterized by H-1 and C-13 NMR and by X-ray crystallography. The ligands, which are derived Via all unusual microbial oxidation of benzoic acid, have been shown to undergo oxidative modification postcomplexation. The factors that influence facial discrimination upon complexation are discussed.

Original language	English
Pages (from-to)	199-204
Number of pages	6
Journal	Organometallics
Volume	29
Issue number	1
DOIs	https://doi.org/10.1021/om9009069
Publication status	Published - 11 Jan 2010

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Lewis_Organimetallics_29_1_199.pdf
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometalics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/om9009069
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Lewis_Organometalics_2009.cif.txt
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometalics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/om9009069

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title = "Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters",

abstract = "Tricarbonyliron(0) complexes of novel cyclohexadiene ligands possessing quaternary centers have been synthesized and characterized by H-1 and C-13 NMR and by X-ray crystallography. The ligands, which are derived Via all unusual microbial oxidation of benzoic acid, have been shown to undergo oxidative modification postcomplexation. The factors that influence facial discrimination upon complexation are discussed.",

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AU - Lewis, S E

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Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters

Abstract

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