Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters

Monika Ali Khan, M F Mahon, A J W Stewart, S E Lewis

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)
288 Downloads (Pure)

Abstract

Tricarbonyliron(0) complexes of novel cyclohexadiene ligands possessing quaternary centers have been synthesized and characterized by H-1 and C-13 NMR and by X-ray crystallography. The ligands, which are derived Via all unusual microbial oxidation of benzoic acid, have been shown to undergo oxidative modification postcomplexation. The factors that influence facial discrimination upon complexation are discussed.
Original languageEnglish
Pages (from-to)199-204
Number of pages6
JournalOrganometallics
Volume29
Issue number1
DOIs
Publication statusPublished - 11 Jan 2010

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