TY - JOUR
T1 - Iron fluorophosphates
AU - Keates, Adam C
AU - Armstrong, Jennifer A
AU - Weller, Mark T
PY - 2013/8/14
Y1 - 2013/8/14
N2 - 18 new iron fluorophosphates and a chlorofluorophosphate have been synthesised hydrothermally in a fluoride-rich medium, using FeF2, FeF3, Fe, HPF6. HCl, monovalent metal fluorides as reactants and amines as templating agents. Products have been fully structurally characterised using single crystal X-ray diffraction, and the stability of some compounds investigated using thermogravimetric analysis. Reaction in fluoride-rich conditions produce ribbon-like, layer and framework structures containing new and unusual structural motifs based on the linking of Fe(O,F)6, PO3F, and PO2(OH,F)2 polyhedra. Structures exhibiting inter-layer spaces and channels are frequently lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Fe(O,F)6 polyhedra.
AB - 18 new iron fluorophosphates and a chlorofluorophosphate have been synthesised hydrothermally in a fluoride-rich medium, using FeF2, FeF3, Fe, HPF6. HCl, monovalent metal fluorides as reactants and amines as templating agents. Products have been fully structurally characterised using single crystal X-ray diffraction, and the stability of some compounds investigated using thermogravimetric analysis. Reaction in fluoride-rich conditions produce ribbon-like, layer and framework structures containing new and unusual structural motifs based on the linking of Fe(O,F)6, PO3F, and PO2(OH,F)2 polyhedra. Structures exhibiting inter-layer spaces and channels are frequently lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Fe(O,F)6 polyhedra.
UR - http://www.scopus.com/inward/record.url?scp=84882970526&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1039/c3dt50324k
U2 - 10.1039/c3dt50324k
DO - 10.1039/c3dt50324k
M3 - Article
C2 - 23770666
SN - 1477-9226
VL - 42
SP - 10715
EP - 10724
JO - Dalton Transactions
JF - Dalton Transactions
IS - 30
ER -