Iron catalyzed dehydrocoupling of amine- and phosphine-boranes

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Catalytic dehydrocoupling methodologies, whereby dihydrogen is released from a substrate (or intermolecularly from two substrates) is a mild and efficient method to construct main group element-main group element bonds, the products of which can be used in advanced materials, and also for the development of hydrogen storage materials. With growing interest in the potential of compounds such as ammonia-borane to act as hydrogen storage materials which contain a high weight% of H2, along with the current heightened interest in base metal catalyzed processes, this review covers recent developments in amine and phosphine dehydrocoupling catalyzed by iron complexes. The complexes employed, products formed and mechanistic proposals will be discussed.
LanguageEnglish
Pages1070-1081
JournalIsrael Journal of Chemistry
Volume57
Issue number12
Early online date27 Jul 2017
DOIs
StatusPublished - 2017

Fingerprint

phosphine
Boranes
Amines
Iron
Hydrogen storage
Substrates
Ammonia
Metals

Cite this

Iron catalyzed dehydrocoupling of amine- and phosphine-boranes. / Coles, Nathan T.; Webster, Ruth L.

In: Israel Journal of Chemistry, Vol. 57, No. 12, 2017, p. 1070-1081.

Research output: Contribution to journalArticle

@article{74470f3e261541bb90bd703a1eda8de5,
title = "Iron catalyzed dehydrocoupling of amine- and phosphine-boranes",
abstract = "Catalytic dehydrocoupling methodologies, whereby dihydrogen is released from a substrate (or intermolecularly from two substrates) is a mild and efficient method to construct main group element-main group element bonds, the products of which can be used in advanced materials, and also for the development of hydrogen storage materials. With growing interest in the potential of compounds such as ammonia-borane to act as hydrogen storage materials which contain a high weight{\%} of H2, along with the current heightened interest in base metal catalyzed processes, this review covers recent developments in amine and phosphine dehydrocoupling catalyzed by iron complexes. The complexes employed, products formed and mechanistic proposals will be discussed.",
author = "Coles, {Nathan T.} and Webster, {Ruth L.}",
year = "2017",
doi = "10.1002/ijch.201700018",
language = "English",
volume = "57",
pages = "1070--1081",
journal = "Israel Journal of Chemistry",
issn = "0021-2148",
publisher = "Wiley-VCH Verlag",
number = "12",

}

TY - JOUR

T1 - Iron catalyzed dehydrocoupling of amine- and phosphine-boranes

AU - Coles, Nathan T.

AU - Webster, Ruth L.

PY - 2017

Y1 - 2017

N2 - Catalytic dehydrocoupling methodologies, whereby dihydrogen is released from a substrate (or intermolecularly from two substrates) is a mild and efficient method to construct main group element-main group element bonds, the products of which can be used in advanced materials, and also for the development of hydrogen storage materials. With growing interest in the potential of compounds such as ammonia-borane to act as hydrogen storage materials which contain a high weight% of H2, along with the current heightened interest in base metal catalyzed processes, this review covers recent developments in amine and phosphine dehydrocoupling catalyzed by iron complexes. The complexes employed, products formed and mechanistic proposals will be discussed.

AB - Catalytic dehydrocoupling methodologies, whereby dihydrogen is released from a substrate (or intermolecularly from two substrates) is a mild and efficient method to construct main group element-main group element bonds, the products of which can be used in advanced materials, and also for the development of hydrogen storage materials. With growing interest in the potential of compounds such as ammonia-borane to act as hydrogen storage materials which contain a high weight% of H2, along with the current heightened interest in base metal catalyzed processes, this review covers recent developments in amine and phosphine dehydrocoupling catalyzed by iron complexes. The complexes employed, products formed and mechanistic proposals will be discussed.

U2 - 10.1002/ijch.201700018

DO - 10.1002/ijch.201700018

M3 - Article

VL - 57

SP - 1070

EP - 1081

JO - Israel Journal of Chemistry

T2 - Israel Journal of Chemistry

JF - Israel Journal of Chemistry

SN - 0021-2148

IS - 12

ER -