Iridium-catalyzed formylation of amines with paraformaldehyde

Ourida Saidi; M J Bamford; A J Blacker; James Lynch; S P Marsden; Pawel Plucinski; R J Watson; Jonathan M J Williams

doi:10.1016/j.tetlet.2010.08.106

Iridium-catalyzed formylation of amines with paraformaldehyde

Ourida Saidi
, M J Bamford
, A J Blacker
, James Lynch
, S P Marsden
, Pawel Plucinski
, R J Watson
, Jonathan M J Williams

Research output: Contribution to journal › Article › peer-review

73 Citations (SciVal)

Abstract

Amines have been formylated using aqueous formaldehyde or paraformaldehyde and the iridium catalyst [Cp*IrI2](2). Paraformaldehyde acts as both a formylating agent and an oxidant.

Original language	English
Pages (from-to)	5804-5806
Number of pages	3
Journal	Tetrahedron Letters
Volume	51
Issue number	44
DOIs	https://doi.org/10.1016/j.tetlet.2010.08.106
Publication status	Published - 3 Nov 2010

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10.1016/j.tetlet.2010.08.106

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title = "Iridium-catalyzed formylation of amines with paraformaldehyde",

abstract = "Amines have been formylated using aqueous formaldehyde or paraformaldehyde and the iridium catalyst [Cp*IrI2](2). Paraformaldehyde acts as both a formylating agent and an oxidant.",

author = "Ourida Saidi and Bamford, \{M J\} and Blacker, \{A J\} and James Lynch and Marsden, \{S P\} and Pawel Plucinski and Watson, \{R J\} and Williams, \{Jonathan M J\}",

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AU - Saidi, Ourida

AU - Bamford, M J

AU - Blacker, A J

AU - Lynch, James

AU - Marsden, S P

AU - Plucinski, Pawel

AU - Watson, R J

AU - Williams, Jonathan M J

PY - 2010/11/3

Y1 - 2010/11/3

N2 - Amines have been formylated using aqueous formaldehyde or paraformaldehyde and the iridium catalyst [Cp*IrI2](2). Paraformaldehyde acts as both a formylating agent and an oxidant.

AB - Amines have been formylated using aqueous formaldehyde or paraformaldehyde and the iridium catalyst [Cp*IrI2](2). Paraformaldehyde acts as both a formylating agent and an oxidant.

UR - https://www.scopus.com/pages/publications/77957567356

UR - http://dx.doi.org/10.1016/j.tetlet.2010.08.106

U2 - 10.1016/j.tetlet.2010.08.106

DO - 10.1016/j.tetlet.2010.08.106

M3 - Article

SN - 0040-4039

VL - 51

SP - 5804

EP - 5806

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 44

ER -

Iridium-catalyzed formylation of amines with paraformaldehyde

Abstract

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Other files and links

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New Generic Synthetic Protocols for Pharmaceutical Intermediates

Hydrogen Transfer Reactions of Amines

Cite this

Iridium-catalyzed formylation of amines with paraformaldehyde

Abstract

Access to Document

Other files and links

Fingerprint

Projects

New Generic Synthetic Protocols for Pharmaceutical Intermediates

Hydrogen Transfer Reactions of Amines

Cite this