Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

Elena Madrid; Mark A. Buckingham; James M. Stone; Adrian T Rogers; William J. Gee; Andrew D. Burrows; Paul R. Raithby; Veronica Celorrio; David J. Fermin; Frank Marken

doi:10.1039/c5cc09780k

Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

Elena Madrid, Mark A. Buckingham, James M. Stone, Adrian T Rogers, William J. Gee, Andrew D. Burrows, Paul R. Raithby, Veronica Celorrio, David J. Fermin, Frank Marken

University of Bristol

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Abstract

Ionic transport (for applications in nanofluidics or membranes) and "ionic diode" phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn²⁺ and 2-methylimidazole as an "asymmetric plug" into a 20 μm diameter pore in a ca. 6 μm thin poly-ethylene-terephthalate (PET) film.

Original language	English
Pages (from-to)	2792-2794
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	13
Early online date	11 Jan 2016
DOIs	https://doi.org/10.1039/c5cc09780k
Publication status	Published - 14 Feb 2016

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10.1039/c5cc09780k

iion flow in a zeoliticAccepted author manuscript, 797 KB

http://dx.doi.org/10.1039/c5cc09780k

Cite this

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title = "Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena",

abstract = "Ionic transport (for applications in nanofluidics or membranes) and {"}ionic diode{"} phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn2+ and 2-methylimidazole as an {"}asymmetric plug{"} into a 20 μm diameter pore in a ca. 6 μm thin poly-ethylene-terephthalate (PET) film.",

author = "Elena Madrid and Buckingham, {Mark A.} and Stone, {James M.} and Rogers, {Adrian T} and Gee, {William J.} and Burrows, {Andrew D.} and Raithby, {Paul R.} and Veronica Celorrio and Fermin, {David J.} and Frank Marken",

year = "2016",

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doi = "10.1039/c5cc09780k",

language = "English",

volume = "52",

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journal = "Chemical Communications",

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T1 - Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

AU - Madrid, Elena

AU - Buckingham, Mark A.

AU - Stone, James M.

AU - Rogers, Adrian T

AU - Gee, William J.

AU - Burrows, Andrew D.

AU - Raithby, Paul R.

AU - Celorrio, Veronica

AU - Fermin, David J.

AU - Marken, Frank

PY - 2016/2/14

Y1 - 2016/2/14

N2 - Ionic transport (for applications in nanofluidics or membranes) and "ionic diode" phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn2+ and 2-methylimidazole as an "asymmetric plug" into a 20 μm diameter pore in a ca. 6 μm thin poly-ethylene-terephthalate (PET) film.

AB - Ionic transport (for applications in nanofluidics or membranes) and "ionic diode" phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn2+ and 2-methylimidazole as an "asymmetric plug" into a 20 μm diameter pore in a ca. 6 μm thin poly-ethylene-terephthalate (PET) film.

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UR - http://dx.doi.org/10.1039/c5cc09780k

U2 - 10.1039/c5cc09780k

DO - 10.1039/c5cc09780k

M3 - Article

AN - SCOPUS:84957927646

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VL - 52

SP - 2792

EP - 2794

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

Abstract

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The UK Catalysis Hub

Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly

Andrew Burrows

Frank Marken

Paul Raithby

MC2-Electron Microscopy (EM)

Cite this

Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

Abstract

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Other files and links

Fingerprint

Projects

The UK Catalysis Hub

Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly

Profiles

Andrew Burrows

Frank Marken

Paul Raithby

Equipment

MC2-Electron Microscopy (EM)

Cite this