Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones

Alexandre Picot, Hellen Dyer, Antoine Buchard, Audrey Auffrant, Laure Vendier, Pascal Le Floch, Sylviane Sabo-Etienne

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H2)(H2NNPP)(PCy3)][BArf4] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.
Original languageEnglish
Pages (from-to)1310-1312
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number4
DOIs
Publication statusPublished - 22 Jan 2010

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Ruthenium
Ketones
Hydrides
ketones
ruthenium
Hydrogenation
hydrogenation
hydrides
Amines
isolation
amines
routes
Ligands
ligands
synthesis
acetophenone

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Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones. / Picot, Alexandre; Dyer, Hellen; Buchard, Antoine; Auffrant, Audrey; Vendier, Laure; Le Floch, Pascal; Sabo-Etienne, Sylviane.

In: Inorganic Chemistry, Vol. 49, No. 4, 22.01.2010, p. 1310-1312.

Research output: Contribution to journalArticle

Picot, Alexandre ; Dyer, Hellen ; Buchard, Antoine ; Auffrant, Audrey ; Vendier, Laure ; Le Floch, Pascal ; Sabo-Etienne, Sylviane. / Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 4. pp. 1310-1312.
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