Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [MonW(3-n)Cp3(CO)6(μ 3-P)] (n = 0-3, Cp = η5-C5H5) and their air oxidation to the corresponding complexes of the μ3-PO ligand

John E. Davies; Marek C. Klunduk; Martin J. Mays; Paul R. Raithby; Gregory P. Shields; Peter K. Tompkin

doi:10.1039/a606262h

Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆(μ ³-P)] (n = 0-3, Cp = η⁵-C₅H₅) and their air oxidation to the corresponding complexes of the μ₃-PO ligand

John E. Davies, Marek C. Klunduk, Martin J. Mays, Paul R. Raithby, Gregory P. Shields, Peter K. Tompkin

Durham University

Research output: Contribution to journal › Article › peer-review

39 Citations (SciVal)

Abstract

Thermoiytic reaction of [MCp(CO)₂(η³-P₃)] with [M′₂Cp₂(CO)₄] (M = M′ = Mo or W, Cp = η⁵-C₅H₅) afforded the dimetallic complexes [Mo_nW_(2-n)Cp₂(CO)₄(μ,η ²-P₂)] (n = 0-2) and the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆-(μ ₃-P)] (n = 0-3). Solutions of these trimetallics were readily oxidised by atmospheric oxygen to the corresponding complexes containing the μ₃-PO ligand, [Mo_nW_(3-n)Cp₃(CO)₆(μ ₃-PO)] (n = 0-3). The complexes [Mo₃Cp₃(CO)₆-(μ₃-PO)], [W₂Cp₂(CO)₄(μ,η²-P ₂)] and [MoWCp₂(CO)₄(μ,η²-P₂)] have been characterised by X-ray diffraction.

Original language	English
Pages (from-to)	715-719
Number of pages	5
Journal	Journal of the Chemical Society - Dalton Transactions
Volume	1997
Issue number	5
DOIs	https://doi.org/10.1039/a606262h
Publication status	Published - 7 Mar 1997

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General Chemistry

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Davies, J. E., Klunduk, M. C., Mays, M. J., Raithby, P. R., Shields, G. P., & Tompkin, P. K. (1997). Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆(μ ³-P)] (n = 0-3, Cp = η⁵-C₅H₅) and their air oxidation to the corresponding complexes of the μ₃-PO ligand. Journal of the Chemical Society - Dalton Transactions, 1997(5), 715-719. https://doi.org/10.1039/a606262h

Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆(μ ³-P)] (n = 0-3, Cp = η⁵-C₅H₅) and their air oxidation to the corresponding complexes of the μ₃-PO ligand. / Davies, John E.; Klunduk, Marek C.; Mays, Martin J. et al.
In: Journal of the Chemical Society - Dalton Transactions, Vol. 1997, No. 5, 07.03.1997, p. 715-719.

Research output: Contribution to journal › Article › peer-review

Davies, JE, Klunduk, MC, Mays, MJ, Raithby, PR, Shields, GP & Tompkin, PK 1997, 'Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆(μ ³-P)] (n = 0-3, Cp = η⁵-C₅H₅) and their air oxidation to the corresponding complexes of the μ₃-PO ligand', Journal of the Chemical Society - Dalton Transactions, vol. 1997, no. 5, pp. 715-719. https://doi.org/10.1039/a606262h

Davies JE, Klunduk MC, Mays MJ, Raithby PR, Shields GP, Tompkin PK. Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆(μ ³-P)] (n = 0-3, Cp = η⁵-C₅H₅) and their air oxidation to the corresponding complexes of the μ₃-PO ligand. Journal of the Chemical Society - Dalton Transactions. 1997 Mar 7;1997(5):715-719. doi: 10.1039/a606262h

Davies, John E. ; Klunduk, Marek C. ; Mays, Martin J. et al. / Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [Mo_nW_(3-n)Cp₃(CO)₆(μ ³-P)] (n = 0-3, Cp = η⁵-C₅H₅) and their air oxidation to the corresponding complexes of the μ₃-PO ligand. In: Journal of the Chemical Society - Dalton Transactions. 1997 ; Vol. 1997, No. 5. pp. 715-719.

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title = "Interconversion of tetrahedranes containing naked phosphorus ligands; synthesis of the trimetallic complexes [MonW(3-n)Cp3(CO)6(μ 3-P)] (n = 0-3, Cp = η5-C5H5) and their air oxidation to the corresponding complexes of the μ3-PO ligand",

abstract = "Thermoiytic reaction of [MCp(CO)2(η3-P3)] with [M′2Cp2(CO)4] (M = M′ = Mo or W, Cp = η5-C5H5) afforded the dimetallic complexes [MonW(2-n)Cp2(CO)4(μ,η 2-P2)] (n = 0-2) and the trimetallic complexes [MonW(3-n)Cp3(CO)6-(μ 3-P)] (n = 0-3). Solutions of these trimetallics were readily oxidised by atmospheric oxygen to the corresponding complexes containing the μ3-PO ligand, [MonW(3-n)Cp3(CO)6(μ 3-PO)] (n = 0-3). The complexes [Mo3Cp3(CO)6-(μ3-PO)], [W2Cp2(CO)4(μ,η2-P 2)] and [MoWCp2(CO)4(μ,η2-P2)] have been characterised by X-ray diffraction.",

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AU - Davies, John E.

AU - Klunduk, Marek C.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Shields, Gregory P.

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N2 - Thermoiytic reaction of [MCp(CO)2(η3-P3)] with [M′2Cp2(CO)4] (M = M′ = Mo or W, Cp = η5-C5H5) afforded the dimetallic complexes [MonW(2-n)Cp2(CO)4(μ,η 2-P2)] (n = 0-2) and the trimetallic complexes [MonW(3-n)Cp3(CO)6-(μ 3-P)] (n = 0-3). Solutions of these trimetallics were readily oxidised by atmospheric oxygen to the corresponding complexes containing the μ3-PO ligand, [MonW(3-n)Cp3(CO)6(μ 3-PO)] (n = 0-3). The complexes [Mo3Cp3(CO)6-(μ3-PO)], [W2Cp2(CO)4(μ,η2-P 2)] and [MoWCp2(CO)4(μ,η2-P2)] have been characterised by X-ray diffraction.

AB - Thermoiytic reaction of [MCp(CO)2(η3-P3)] with [M′2Cp2(CO)4] (M = M′ = Mo or W, Cp = η5-C5H5) afforded the dimetallic complexes [MonW(2-n)Cp2(CO)4(μ,η 2-P2)] (n = 0-2) and the trimetallic complexes [MonW(3-n)Cp3(CO)6-(μ 3-P)] (n = 0-3). Solutions of these trimetallics were readily oxidised by atmospheric oxygen to the corresponding complexes containing the μ3-PO ligand, [MonW(3-n)Cp3(CO)6(μ 3-PO)] (n = 0-3). The complexes [Mo3Cp3(CO)6-(μ3-PO)], [W2Cp2(CO)4(μ,η2-P 2)] and [MoWCp2(CO)4(μ,η2-P2)] have been characterised by X-ray diffraction.

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