Interchange of SPh and PPh2 groups at a dicobalt centre: Crystal and molecular structures of [Co2(μ-PPh2){μ-SPhC(O) CHCH}(CO)4] and [CO2(μ-SPh){μ-PPh 2CHCHC(O)}(CO)2{P(OMe)3}2]

Andrew J. Edwards; Avelino Martín; Martin J. Mays; Paul R. Raithby; Gregory A. Solan

doi:10.1039/C39920001416

Interchange of SPh and PPh₂ groups at a dicobalt centre: Crystal and molecular structures of [Co₂(μ-PPh₂){μ-SPhC(O) CHCH}(CO)₄] and [CO₂(μ-SPh){μ-PPh ₂CHCHC(O)}(CO)₂{P(OMe)₃}₂]

Andrew J. Edwards
, Avelino Martín
, Martin J. Mays
, Paul R. Raithby
, Gregory A. Solan

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The thermal reaction of [Co₂(μ-PPh₂){μ-SPhC(O) CHCH}(CO)₄] with P(OMe)₃ leads, in addition to carbonyl substitution, to a novel ligand rearrangement in which the PPh₂ and SPh groups interchange positions, giving the new organometallic derivative [Co₂(μ-SPh){μ-PPh₂CHCHC(O)}(CO)₂{P(OMe) ₃}₂]; both complexes are characterised by X-ray diffraction studies.

Original language	English
Pages (from-to)	1416-1418
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39920001416
Publication status	Published - 1992

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39920001416

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Edwards, A. J., Martín, A., Mays, M. J., Raithby, P. R., & Solan, G. A. (1992). Interchange of SPh and PPh₂ groups at a dicobalt centre: Crystal and molecular structures of [Co₂(μ-PPh₂){μ-SPhC(O) CHCH}(CO)₄] and [CO₂(μ-SPh){μ-PPh ₂CHCHC(O)}(CO)₂{P(OMe)₃}₂]. Journal of the Chemical Society, Chemical Communications, (19), 1416-1418. https://doi.org/10.1039/C39920001416

Interchange of SPh and PPh₂ groups at a dicobalt centre: Crystal and molecular structures of [Co₂(μ-PPh₂){μ-SPhC(O) CHCH}(CO)₄] and [CO₂(μ-SPh){μ-PPh ₂CHCHC(O)}(CO)₂{P(OMe)₃}₂]. / Edwards, Andrew J.; Martín, Avelino; Mays, Martin J. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 19, 1992, p. 1416-1418.

Research output: Contribution to journal › Article › peer-review

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title = "Interchange of SPh and PPh2 groups at a dicobalt centre: Crystal and molecular structures of [Co2(μ-PPh2)\{μ-SPhC(O) CHCH\}(CO)4] and [CO2(μ-SPh)\{μ-PPh 2CHCHC(O)\}(CO)2\{P(OMe)3\}2]",

abstract = "The thermal reaction of [Co2(μ-PPh2)\{μ-SPhC(O) CHCH\}(CO)4] with P(OMe)3 leads, in addition to carbonyl substitution, to a novel ligand rearrangement in which the PPh2 and SPh groups interchange positions, giving the new organometallic derivative [Co2(μ-SPh)\{μ-PPh2CHCHC(O)\}(CO)2\{P(OMe) 3\}2]; both complexes are characterised by X-ray diffraction studies.",

author = "Edwards, \{Andrew J.\} and Avelino Mart{\'i}n and Mays, \{Martin J.\} and Raithby, \{Paul R.\} and Solan, \{Gregory A.\}",

year = "1992",

doi = "10.1039/C39920001416",

language = "English",

pages = "1416--1418",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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TY - JOUR

T1 - Interchange of SPh and PPh2 groups at a dicobalt centre

T2 - Crystal and molecular structures of [Co2(μ-PPh2){μ-SPhC(O) CHCH}(CO)4] and [CO2(μ-SPh){μ-PPh 2CHCHC(O)}(CO)2{P(OMe)3}2]

AU - Edwards, Andrew J.

AU - Martín, Avelino

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Solan, Gregory A.

PY - 1992

Y1 - 1992

N2 - The thermal reaction of [Co2(μ-PPh2){μ-SPhC(O) CHCH}(CO)4] with P(OMe)3 leads, in addition to carbonyl substitution, to a novel ligand rearrangement in which the PPh2 and SPh groups interchange positions, giving the new organometallic derivative [Co2(μ-SPh){μ-PPh2CHCHC(O)}(CO)2{P(OMe) 3}2]; both complexes are characterised by X-ray diffraction studies.

AB - The thermal reaction of [Co2(μ-PPh2){μ-SPhC(O) CHCH}(CO)4] with P(OMe)3 leads, in addition to carbonyl substitution, to a novel ligand rearrangement in which the PPh2 and SPh groups interchange positions, giving the new organometallic derivative [Co2(μ-SPh){μ-PPh2CHCHC(O)}(CO)2{P(OMe) 3}2]; both complexes are characterised by X-ray diffraction studies.

UR - https://www.scopus.com/pages/publications/37049083340

U2 - 10.1039/C39920001416

DO - 10.1039/C39920001416

M3 - Article

AN - SCOPUS:37049083340

SN - 0022-4936

SP - 1416

EP - 1418

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 19

ER -

Interchange of SPh and PPh₂ groups at a dicobalt centre: Crystal and molecular structures of [Co₂(μ-PPh₂){μ-SPhC(O) CHCH}(CO)₄] and [CO₂(μ-SPh){μ-PPh ₂CHCHC(O)}(CO)₂{P(OMe)₃}₂]

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