Abstract
The thermal reaction of [Co2(μ-PPh2){μ-SPhC(O) CHCH}(CO)4] with P(OMe)3 leads, in addition to carbonyl substitution, to a novel ligand rearrangement in which the PPh2 and SPh groups interchange positions, giving the new organometallic derivative [Co2(μ-SPh){μ-PPh2CHCHC(O)}(CO)2{P(OMe) 3}2]; both complexes are characterised by X-ray diffraction studies.
Original language | English |
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Pages (from-to) | 1416-1418 |
Number of pages | 3 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 19 |
DOIs | |
Publication status | Published - 1992 |
ASJC Scopus subject areas
- Molecular Medicine