In situ detection of free and trapped electrons in dye-sensitized solar cells by photo-induced microwave reflectance measurements

H.K. Dunn, L.M. Peter, S.J. Bingham, E. Maluta, A.B. Walker

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Abstract

In order to study the behavior of photoinjected electrons in dye-sensitized solar cells (DSC), steady-state microwave reflectance measurements (33 GHz, Ka band) have been carried out on a working cell filled with electrolyte. The experimental arrangement allowed simultaneous measurement of the light-induced changes in microwave reflectance and open circuit voltage as a function of illumination intensity. In addition, frequency-resolved intensity-modulated microwave reflectance measurements were used to characterize the relaxation of the electron concentration at open circuit by interfacial transfer to tri-iodide ions in the electrolyte. The dependence of the free and trapped electron concentrations on open circuit voltage were derived, respectively, from conductivity data (obtained by impedance spectroscopy) and from light-induced near IR transmittance changes. These electron concentrations were used in the fitting of the microwave reflectivity response, with electron mobility as the main variable. Changes in the complex permittivity of the mesoporous films were calculated using Drude-Zener theory for free electrons and a simple harmonic oscillator model for trapped electrons. Comparison of the calculated microwave reflectance changes with the experimental data showed that the experimental response arises primarily from the perturbation of the real component of the complex permittivity by the high concentration of trapped electrons present in the DSC under illumination. The results suggest that caution is needed when interpreting the results of microwave reflectance measurements on materials with high concentrations of electron (or hole) traps, since an a priori assumption that the microwave response is solely determined by changes in conductivity (i.e., by free electrons) may be incorrect. The intensity-modulated microwave reflectance measurements showed that relaxation of the free and trapped electron concentrations occurs on a similar time scale, confirming that the free and trapped electron populations remain in quasi-equilibrium during the decay of the electron concentration.
LanguageEnglish
Pages22063-22072
Number of pages10
JournalJournal of Physical Chemistry C
Volume116
Issue number41
DOIs
StatusPublished - 18 Oct 2012

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Reflectometers
free electrons
solar cells
dyes
Microwaves
reflectance
microwaves
Electrons
electrons
open circuit voltage
Open circuit voltage
Electrolytes
illumination
Dye-sensitized solar cells
Permittivity
electrolytes
permittivity
Lighting
conductivity
Hole traps

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In situ detection of free and trapped electrons in dye-sensitized solar cells by photo-induced microwave reflectance measurements. / Dunn, H.K.; Peter, L.M.; Bingham, S.J.; Maluta, E.; Walker, A.B.

In: Journal of Physical Chemistry C, Vol. 116, No. 41, 18.10.2012, p. 22063-22072.

Research output: Contribution to journalArticle

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AB - In order to study the behavior of photoinjected electrons in dye-sensitized solar cells (DSC), steady-state microwave reflectance measurements (33 GHz, Ka band) have been carried out on a working cell filled with electrolyte. The experimental arrangement allowed simultaneous measurement of the light-induced changes in microwave reflectance and open circuit voltage as a function of illumination intensity. In addition, frequency-resolved intensity-modulated microwave reflectance measurements were used to characterize the relaxation of the electron concentration at open circuit by interfacial transfer to tri-iodide ions in the electrolyte. The dependence of the free and trapped electron concentrations on open circuit voltage were derived, respectively, from conductivity data (obtained by impedance spectroscopy) and from light-induced near IR transmittance changes. These electron concentrations were used in the fitting of the microwave reflectivity response, with electron mobility as the main variable. Changes in the complex permittivity of the mesoporous films were calculated using Drude-Zener theory for free electrons and a simple harmonic oscillator model for trapped electrons. Comparison of the calculated microwave reflectance changes with the experimental data showed that the experimental response arises primarily from the perturbation of the real component of the complex permittivity by the high concentration of trapped electrons present in the DSC under illumination. The results suggest that caution is needed when interpreting the results of microwave reflectance measurements on materials with high concentrations of electron (or hole) traps, since an a priori assumption that the microwave response is solely determined by changes in conductivity (i.e., by free electrons) may be incorrect. The intensity-modulated microwave reflectance measurements showed that relaxation of the free and trapped electron concentrations occurs on a similar time scale, confirming that the free and trapped electron populations remain in quasi-equilibrium during the decay of the electron concentration.

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