Abstract
The harvesting of waste heat is attracting increasing attention, due to its abundance and potential benefits to the environment. However, the need for high heat transfer rates in thermal harvesting systems is a longstanding obstacle for their practical application. In this work, we construct thermally conductive networks in Pb[(MnxNb1−x)1/2(MnxSb1−x)1/2]y(Zr95Ti5)1−yO3 (lead magnesium niobate–lead antimony–manganese–lead zirconate titanate: PMN–PMS–PZT) ceramics to improve heat transfer and enhance their ferroelectric properties by use of a thermally conductive AlN additive dispersed in the ceramic matrix. The ferroelectric properties, pyroelectric coefficient and thermal conductivity of the PMN–PMS–PZT: AlN composite materials are influenced by the AlN content as a result of the formation of random bridges or thermally conductive networks for phonon transfer in the ceramic matrix, thereby leading to high heat transfer. For a PMN–PMS–PZT composite with a 0.2 wt% AlN content, the ferroelectric properties, pyroelectric coefficient and thermal conductivity are shown to be enhanced owing to the improved crystallinity and density, and the relative permittivity is also reduced, which results in optimized pyroelectric figure of merits. This combination of materials property enhancements is shown to be beneficial for high performance pyroelectric materials in devices for energy harvesting applications.
Original language | English |
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Pages (from-to) | 5040-5051 |
Number of pages | 12 |
Journal | Journal of Materials Chemistry A |
Volume | 6 |
Issue number | 12 |
Early online date | 26 Feb 2018 |
DOIs | |
Publication status | Published - 28 Mar 2018 |
ASJC Scopus subject areas
- Chemistry(all)
- Renewable Energy, Sustainability and the Environment
- Materials Science(all)
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Chris Bowen
- Department of Mechanical Engineering - Professor
- Centre for Sustainable and Circular Technologies (CSCT)
- Centre for Nanoscience and Nanotechnology
- Institute for Mathematical Innovation (IMI)
- Faculty of Engineering and Design - Associate Dean (Research)
- Institute for Sustainability
- Centre for Integrated Materials, Processes & Structures (IMPS)
- EPSRC Centre for Doctoral Training in Advanced Automotive Propulsion Systems (AAPS CDT)
- Institute for Advanced Automotive Propulsion Systems (IAAPS)
Person: Research & Teaching, Core staff, Affiliate staff