Identification of Erbium(III) Chloride Solvate ErCl3(thf)3.5:Crystal and Molecular Structure of the Ion-pair [trans-ErCl2(thf)5][trans-ErCl4(thf) 2]

G. R. Willey; T. J. Woodman; W. Errington

Identification of Erbium(III) Chloride Solvate ErCl₃(thf)_3.5:Crystal and Molecular Structure of the Ion-pair [trans-ErCl₂(thf)₅][trans-ErCl₄(thf) ₂]

G. R. Willey
, T. J. Woodman
, W. Errington

University of Warwick

Research output: Contribution to journal › Article › peer-review

8 Citations (SciVal)

Abstract

ErCl₃(thf)_3.5 has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl₂(thf)₅][trans-ErCl₄(thf) ₂]. The monocation features a seven-coordinate erbium atom with a trans-ErCl₂ unit (Er-Cl, 2.563(2) Å) surrounded by five tetrahydrofuran molecules (Er-O, in the range 2.383(8)-2.393(8) Å) in a regular pentagonal bipyramidal geometry. The anion is six-coordinate with an octahedral metal geometry comprising four equatorial chlorine atoms (Er-Cl, 2.593(3) and 2.609(3) Å) and two axial tetrahydrofuran molecules (Er-O, 2.313(9) Å).

Original language	English
Pages (from-to)	435-438
Number of pages	4
Journal	Journal of the Indian Chemical Society
Volume	75
Issue number	8
Publication status	Published - 31 Aug 1998

ASJC Scopus subject areas

Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Electrochemistry

Cite this

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title = "Identification of Erbium(III) Chloride Solvate ErCl3(thf)3.5:Crystal and Molecular Structure of the Ion-pair [trans-ErCl2(thf)5][trans-ErCl4(thf) 2]",

abstract = "ErCl3(thf)3.5 has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl2(thf)5][trans-ErCl4(thf) 2]. The monocation features a seven-coordinate erbium atom with a trans-ErCl2 unit (Er-Cl, 2.563(2) {\AA}) surrounded by five tetrahydrofuran molecules (Er-O, in the range 2.383(8)-2.393(8) {\AA}) in a regular pentagonal bipyramidal geometry. The anion is six-coordinate with an octahedral metal geometry comprising four equatorial chlorine atoms (Er-Cl, 2.593(3) and 2.609(3) {\AA}) and two axial tetrahydrofuran molecules (Er-O, 2.313(9) {\AA}).",

author = "Willey, \{G. R.\} and Woodman, \{T. J.\} and W. Errington",

year = "1998",

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journal = "Journal of the Indian Chemical Society",

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TY - JOUR

T1 - Identification of Erbium(III) Chloride Solvate ErCl3(thf)3.5:Crystal and Molecular Structure of the Ion-pair [trans-ErCl2(thf)5][trans-ErCl4(thf) 2]

AU - Willey, G. R.

AU - Woodman, T. J.

AU - Errington, W.

PY - 1998/8/31

Y1 - 1998/8/31

N2 - ErCl3(thf)3.5 has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl2(thf)5][trans-ErCl4(thf) 2]. The monocation features a seven-coordinate erbium atom with a trans-ErCl2 unit (Er-Cl, 2.563(2) Å) surrounded by five tetrahydrofuran molecules (Er-O, in the range 2.383(8)-2.393(8) Å) in a regular pentagonal bipyramidal geometry. The anion is six-coordinate with an octahedral metal geometry comprising four equatorial chlorine atoms (Er-Cl, 2.593(3) and 2.609(3) Å) and two axial tetrahydrofuran molecules (Er-O, 2.313(9) Å).

AB - ErCl3(thf)3.5 has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl2(thf)5][trans-ErCl4(thf) 2]. The monocation features a seven-coordinate erbium atom with a trans-ErCl2 unit (Er-Cl, 2.563(2) Å) surrounded by five tetrahydrofuran molecules (Er-O, in the range 2.383(8)-2.393(8) Å) in a regular pentagonal bipyramidal geometry. The anion is six-coordinate with an octahedral metal geometry comprising four equatorial chlorine atoms (Er-Cl, 2.593(3) and 2.609(3) Å) and two axial tetrahydrofuran molecules (Er-O, 2.313(9) Å).

UR - https://www.scopus.com/pages/publications/0010621678

M3 - Article

AN - SCOPUS:0010621678

SN - 0019-4522

VL - 75

SP - 435

EP - 438

JO - Journal of the Indian Chemical Society

JF - Journal of the Indian Chemical Society

IS - 8

ER -

Identification of Erbium(III) Chloride Solvate ErCl₃(thf)_3.5:Crystal and Molecular Structure of the Ion-pair [trans-ErCl₂(thf)₅][trans-ErCl₄(thf) ₂]

Abstract

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