Projects per year
Abstract
The hydroboration of aldehydes, ketones and CO2 is demonstrated using a cheap and air stable [Fe(salen)]2-μ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)2]-μ-oxo pre-catalyst shows good efficacy at reducing “wet” CO2 with HBpin at room temperature.
Original language | English |
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Pages (from-to) | 10696-10700 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 50 |
Issue number | 31 |
Early online date | 20 Jul 2021 |
DOIs | |
Publication status | Published - 21 Aug 2021 |
ASJC Scopus subject areas
- Inorganic Chemistry
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Dive into the research topics of 'Hydroboration of aldehydes, ketones and CO 2under mild conditions mediated by iron(iii) salen complexes'. Together they form a unique fingerprint.Projects
- 1 Finished
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EC Fellowship - Cast Iron Catalysis: New Protocols for the Synthesis of Carbon-Phosphorus Bonds
Webster, R. (PI)
Engineering and Physical Sciences Research Council
3/12/17 → 2/03/24
Project: Research council