Hydroboration of aldehydes, ketones and CO
            2under mild conditions mediated by iron(iii) salen complexes

Samantha Lau; Cei Provis-Evans; Alexander James; Ruth Webster

doi:10.1039/D1DT02092G

Hydroboration of aldehydes, ketones and CO ₂under mild conditions mediated by iron(iii) salen complexes

Samantha Lau, Cei Provis-Evans, Alexander James, Ruth Webster

Research output: Contribution to journal › Article › peer-review

19 Citations (SciVal)

Abstract

The hydroboration of aldehydes, ketones and CO2 is demonstrated using a cheap and air stable [Fe(salen)]2-μ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)2]-μ-oxo pre-catalyst shows good efficacy at reducing “wet” CO2 with HBpin at room temperature.

Original language	English
Pages (from-to)	10696-10700
Number of pages	5
Journal	Dalton Transactions
Volume	50
Issue number	31
Early online date	20 Jul 2021
DOIs	https://doi.org/10.1039/D1DT02092G
Publication status	Published - 21 Aug 2021

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/D1DT02092GLicence: CC BY

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abstract = "The hydroboration of aldehydes, ketones and CO2 is demonstrated using a cheap and air stable [Fe(salen)]2-μ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)2]-μ-oxo pre-catalyst shows good efficacy at reducing “wet” CO2 with HBpin at room temperature.",

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AU - Lau, Samantha

AU - Provis-Evans, Cei

AU - James, Alexander

AU - Webster, Ruth

PY - 2021/8/21

Y1 - 2021/8/21

N2 - The hydroboration of aldehydes, ketones and CO2 is demonstrated using a cheap and air stable [Fe(salen)]2-μ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)2]-μ-oxo pre-catalyst shows good efficacy at reducing “wet” CO2 with HBpin at room temperature.

AB - The hydroboration of aldehydes, ketones and CO2 is demonstrated using a cheap and air stable [Fe(salen)]2-μ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)2]-μ-oxo pre-catalyst shows good efficacy at reducing “wet” CO2 with HBpin at room temperature.

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U2 - 10.1039/D1DT02092G

DO - 10.1039/D1DT02092G

M3 - Article

SN - 1477-9226

VL - 50

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EP - 10700

JO - Dalton Transactions

JF - Dalton Transactions

IS - 31

ER -

Hydroboration of aldehydes, ketones and CO ₂under mild conditions mediated by iron(iii) salen complexes

Abstract

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EC Fellowship - Cast Iron Catalysis: New Protocols for the Synthesis of Carbon-Phosphorus Bonds

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Hydroboration of aldehydes, ketones and CO 2under mild conditions mediated by iron(iii) salen complexes

Abstract

ASJC Scopus subject areas

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EC Fellowship - Cast Iron Catalysis: New Protocols for the Synthesis of Carbon-Phosphorus Bonds

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Hydroboration of aldehydes, ketones and CO ₂under mild conditions mediated by iron(iii) salen complexes