How Ultranarrow Gap Symmetries Control Plasmonic Nanocavity Modes: From Cubes to Spheres in the Nanoparticle-on-Mirror

Rohit Chikkaraddy, Xuezhi Zheng, Felix Benz, Laura J. Brooks, Bart De Nijs, Cloudy Carnegie, Marie Elena Kleemann, Jan Mertens, Richard W. Bowman, Guy A.E. Vandenbosch, Victor V. Moshchalkov, Jeremy J. Baumberg

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Plasmonic nanocavities with sub-5-nm gaps between nanoparticles support multiple resonances possessing ultra-high-field confinement and enhancements. Here we systematically compare the two fundamentally different resonant gap modes: transverse waveguide (s) and antenna modes (l), which, despite both tightly confining light within the gap, have completely different near-field and far-field radiation patterns. By varying the gap size, both experimentally and theoretically, we show how changing the nanoparticle shape from sphere to cube alters coupling of s and l modes, resulting in strongly hybridized (j) modes. Through rigorous group representation analysis we identify their composition and coupling. This systematic analysis of the Purcell factors shows that modes with optical field perpendicular to the gap are best to probe the optical properties of cavity-bound emitters, such as single molecules.

Original languageEnglish
Pages (from-to)469-475
Number of pages7
JournalACS Photonics
Volume4
Issue number3
Early online date13 Feb 2017
DOIs
Publication statusPublished - 15 Mar 2017

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Keywords

  • metasurfaces
  • nanocavities
  • patch antennas
  • plasmonics
  • Purcell factor
  • SERS
  • strong coupling

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biotechnology
  • Atomic and Molecular Physics, and Optics
  • Electrical and Electronic Engineering

Cite this

Chikkaraddy, R., Zheng, X., Benz, F., Brooks, L. J., De Nijs, B., Carnegie, C., ... Baumberg, J. J. (2017). How Ultranarrow Gap Symmetries Control Plasmonic Nanocavity Modes: From Cubes to Spheres in the Nanoparticle-on-Mirror. ACS Photonics, 4(3), 469-475. https://doi.org/10.1021/acsphotonics.6b00908