Homogeneous catalysis with organometallic complexes of group 2

M.R. Crimmin, M.S. Hill

Research output: Chapter in Book/Report/Conference proceedingChapter

71 Citations (Scopus)

Abstract

This chapter provides details of the recent progress in heavier Group 2-catalyzed small molecule transformations mediated by well-defined heteroleptic and homoleptic complexes of the form LMX or MX2, where L is a monoanionic ligand and X is a reactive σ-bonded substituent and M = Mg, Ca, Sr, and Ba. The intra- and intermolecular heterofunctionalization (hydroamination, hydrophosphination, hydrosilylation, hydroboration, hydrogenation, and hydroacetylation) of alkenes, alkynes, dienes, carbodiimides, isocyanates, pyridines, quinolines, and ketones is discussed, along with the dimerization of aldehydes, the trimerization of isocyanates, and the dehydrogenation of amine-boranes and the dehydrogenative coupling of amines with silanes. While studies in this field have focused largely on biocompatible and inexpensive catalysts of calcium and the heavier elements, the field has renewed interest in the chemistry of organomagnesium complexes.

Original languageEnglish
Title of host publicationAlkaline-Earth Metal Compounds
Subtitle of host publicationOddities and Applications
EditorsSjoerd Harder
Place of PublicationBerlin
PublisherSpringer
Pages191-242
Number of pages52
ISBN (Print)9783642362699
DOIs
Publication statusPublished - 2013

Publication series

NameTopics in Organometallic Chemistry
PublisherSpringer
Volume45
ISSN (Print)1436-6002

Fingerprint

Isocyanates
Organometallics
Catalysis
Amines
Quinolines
Boranes
Pyridines
Carbodiimides
Hydrosilylation
Silanes
Alkynes
Dimerization
Alkenes
Dehydrogenation
Ketones
Aldehydes
Chemical elements
Hydrogenation
Ligands
Calcium

Cite this

Crimmin, M. R., & Hill, M. S. (2013). Homogeneous catalysis with organometallic complexes of group 2. In S. Harder (Ed.), Alkaline-Earth Metal Compounds: Oddities and Applications (pp. 191-242). (Topics in Organometallic Chemistry; Vol. 45). Berlin: Springer. https://doi.org/10.1007/978-3-642-36270-5_6

Homogeneous catalysis with organometallic complexes of group 2. / Crimmin, M.R.; Hill, M.S.

Alkaline-Earth Metal Compounds: Oddities and Applications. ed. / Sjoerd Harder. Berlin : Springer, 2013. p. 191-242 (Topics in Organometallic Chemistry; Vol. 45).

Research output: Chapter in Book/Report/Conference proceedingChapter

Crimmin, MR & Hill, MS 2013, Homogeneous catalysis with organometallic complexes of group 2. in S Harder (ed.), Alkaline-Earth Metal Compounds: Oddities and Applications. Topics in Organometallic Chemistry, vol. 45, Springer, Berlin, pp. 191-242. https://doi.org/10.1007/978-3-642-36270-5_6
Crimmin MR, Hill MS. Homogeneous catalysis with organometallic complexes of group 2. In Harder S, editor, Alkaline-Earth Metal Compounds: Oddities and Applications. Berlin: Springer. 2013. p. 191-242. (Topics in Organometallic Chemistry). https://doi.org/10.1007/978-3-642-36270-5_6
Crimmin, M.R. ; Hill, M.S. / Homogeneous catalysis with organometallic complexes of group 2. Alkaline-Earth Metal Compounds: Oddities and Applications. editor / Sjoerd Harder. Berlin : Springer, 2013. pp. 191-242 (Topics in Organometallic Chemistry).
@inbook{ce445b4b387445ec99cfb2440fcb1f4d,
title = "Homogeneous catalysis with organometallic complexes of group 2",
abstract = "This chapter provides details of the recent progress in heavier Group 2-catalyzed small molecule transformations mediated by well-defined heteroleptic and homoleptic complexes of the form LMX or MX2, where L is a monoanionic ligand and X is a reactive σ-bonded substituent and M = Mg, Ca, Sr, and Ba. The intra- and intermolecular heterofunctionalization (hydroamination, hydrophosphination, hydrosilylation, hydroboration, hydrogenation, and hydroacetylation) of alkenes, alkynes, dienes, carbodiimides, isocyanates, pyridines, quinolines, and ketones is discussed, along with the dimerization of aldehydes, the trimerization of isocyanates, and the dehydrogenation of amine-boranes and the dehydrogenative coupling of amines with silanes. While studies in this field have focused largely on biocompatible and inexpensive catalysts of calcium and the heavier elements, the field has renewed interest in the chemistry of organomagnesium complexes.",
author = "M.R. Crimmin and M.S. Hill",
year = "2013",
doi = "10.1007/978-3-642-36270-5_6",
language = "English",
isbn = "9783642362699",
series = "Topics in Organometallic Chemistry",
publisher = "Springer",
pages = "191--242",
editor = "Sjoerd Harder",
booktitle = "Alkaline-Earth Metal Compounds",

}

TY - CHAP

T1 - Homogeneous catalysis with organometallic complexes of group 2

AU - Crimmin, M.R.

AU - Hill, M.S.

PY - 2013

Y1 - 2013

N2 - This chapter provides details of the recent progress in heavier Group 2-catalyzed small molecule transformations mediated by well-defined heteroleptic and homoleptic complexes of the form LMX or MX2, where L is a monoanionic ligand and X is a reactive σ-bonded substituent and M = Mg, Ca, Sr, and Ba. The intra- and intermolecular heterofunctionalization (hydroamination, hydrophosphination, hydrosilylation, hydroboration, hydrogenation, and hydroacetylation) of alkenes, alkynes, dienes, carbodiimides, isocyanates, pyridines, quinolines, and ketones is discussed, along with the dimerization of aldehydes, the trimerization of isocyanates, and the dehydrogenation of amine-boranes and the dehydrogenative coupling of amines with silanes. While studies in this field have focused largely on biocompatible and inexpensive catalysts of calcium and the heavier elements, the field has renewed interest in the chemistry of organomagnesium complexes.

AB - This chapter provides details of the recent progress in heavier Group 2-catalyzed small molecule transformations mediated by well-defined heteroleptic and homoleptic complexes of the form LMX or MX2, where L is a monoanionic ligand and X is a reactive σ-bonded substituent and M = Mg, Ca, Sr, and Ba. The intra- and intermolecular heterofunctionalization (hydroamination, hydrophosphination, hydrosilylation, hydroboration, hydrogenation, and hydroacetylation) of alkenes, alkynes, dienes, carbodiimides, isocyanates, pyridines, quinolines, and ketones is discussed, along with the dimerization of aldehydes, the trimerization of isocyanates, and the dehydrogenation of amine-boranes and the dehydrogenative coupling of amines with silanes. While studies in this field have focused largely on biocompatible and inexpensive catalysts of calcium and the heavier elements, the field has renewed interest in the chemistry of organomagnesium complexes.

UR - http://www.scopus.com/inward/record.url?scp=84881327844&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1007/978-3-642-36270-5_6

U2 - 10.1007/978-3-642-36270-5_6

DO - 10.1007/978-3-642-36270-5_6

M3 - Chapter

SN - 9783642362699

T3 - Topics in Organometallic Chemistry

SP - 191

EP - 242

BT - Alkaline-Earth Metal Compounds

A2 - Harder, Sjoerd

PB - Springer

CY - Berlin

ER -