Highly efficient ruthenium-catalyzed oxime to amide rearrangement

N A Owston; A J Parker; J M J Williams

doi:10.1021/ol701445n

Highly efficient ruthenium-catalyzed oxime to amide rearrangement

N A Owston, A J Parker, J M J Williams

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

253 Citations (SciVal)

Abstract

A wide range of aldoximes has been converted into the corresponding amides using the ruthenium-based catalyst Ru(PPh3)(3)(CO)H-2/dppe/TsOH. The amides are generated in high yield and selectivity, with catalyst loading as low as 0.04 mol %.

Original language	English
Pages (from-to)	3599-3601
Number of pages	3
Journal	Organic Letters
Volume	9
Issue number	18
DOIs	https://doi.org/10.1021/ol701445n
Publication status	Published - 2007

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ID number: ISI:000248929400029

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10.1021/ol701445n

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title = "Highly efficient ruthenium-catalyzed oxime to amide rearrangement",

abstract = "A wide range of aldoximes has been converted into the corresponding amides using the ruthenium-based catalyst Ru(PPh3)(3)(CO)H-2/dppe/TsOH. The amides are generated in high yield and selectivity, with catalyst loading as low as 0.04 mol \%.",

author = "Owston, \{N A\} and Parker, \{A J\} and Williams, \{J M J\}",

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journal = "Organic Letters",

issn = "1523-7060",

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T1 - Highly efficient ruthenium-catalyzed oxime to amide rearrangement

AU - Owston, N A

AU - Parker, A J

AU - Williams, J M J

N1 - ID number: ISI:000248929400029

PY - 2007

Y1 - 2007

N2 - A wide range of aldoximes has been converted into the corresponding amides using the ruthenium-based catalyst Ru(PPh3)(3)(CO)H-2/dppe/TsOH. The amides are generated in high yield and selectivity, with catalyst loading as low as 0.04 mol %.

AB - A wide range of aldoximes has been converted into the corresponding amides using the ruthenium-based catalyst Ru(PPh3)(3)(CO)H-2/dppe/TsOH. The amides are generated in high yield and selectivity, with catalyst loading as low as 0.04 mol %.

U2 - 10.1021/ol701445n

DO - 10.1021/ol701445n

M3 - Article

SN - 1523-7060

VL - 9

SP - 3599

EP - 3601

JO - Organic Letters

JF - Organic Letters

IS - 18

ER -

Highly efficient ruthenium-catalyzed oxime to amide rearrangement

Abstract

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