Highly Active Mg(II) and Zn(II) complexes for the ring opening polymerisation of lactide

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Abstract

A range of simple ethylenediamine based Zn(II) and Mg(II) complexes have been prepared and their structures determined via NMR spectroscopy and X-ray crystallography. Preparation of these complexes was also demonstrated to be scalable, with 25 g of Zn(1)2 being readily produced. These complexes were trialed for the ring opening polymerisation (ROP) of lactide under industrial relevant conditions. Their reactivity has been related to their structure in solution. Incredibly high activity is achieved in the majority of cases including low catalytic loading and high temperatures, at industrially relevant conditions (180 °C 10,000:1:100 [LA]:[Zn]:[BnOH]), with high conversion achieved within 10 minutes and TOFs in excess of 100,000 hr-1 achieved. The performance of these initiators for polymer production is supported by GPC, DSC and IR spectroscopy which all highlight the excellent control achieved.
Original languageEnglish
Pages (from-to)5339-5347
Number of pages9
JournalPolymer Chemistry
Volume9
Issue number44
Early online date18 Oct 2018
DOIs
Publication statusPublished - 28 Nov 2018

ASJC Scopus subject areas

  • Bioengineering
  • Biochemistry
  • Polymers and Plastics
  • Organic Chemistry

Cite this

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title = "Highly Active Mg(II) and Zn(II) complexes for the ring opening polymerisation of lactide",
abstract = "A range of simple ethylenediamine based Zn(II) and Mg(II) complexes have been prepared and their structures determined via NMR spectroscopy and X-ray crystallography. Preparation of these complexes was also demonstrated to be scalable, with 25 g of Zn(1)2 being readily produced. These complexes were trialed for the ring opening polymerisation (ROP) of lactide under industrial relevant conditions. Their reactivity has been related to their structure in solution. Incredibly high activity is achieved in the majority of cases including low catalytic loading and high temperatures, at industrially relevant conditions (180 °C 10,000:1:100 [LA]:[Zn]:[BnOH]), with high conversion achieved within 10 minutes and TOFs in excess of 100,000 hr-1 achieved. The performance of these initiators for polymer production is supported by GPC, DSC and IR spectroscopy which all highlight the excellent control achieved.",
author = "Paul McKeown and Strachan Mccormick and Mary Mahon and Matthew Jones",
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AU - McKeown, Paul

AU - Mccormick, Strachan

AU - Mahon, Mary

AU - Jones, Matthew

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N2 - A range of simple ethylenediamine based Zn(II) and Mg(II) complexes have been prepared and their structures determined via NMR spectroscopy and X-ray crystallography. Preparation of these complexes was also demonstrated to be scalable, with 25 g of Zn(1)2 being readily produced. These complexes were trialed for the ring opening polymerisation (ROP) of lactide under industrial relevant conditions. Their reactivity has been related to their structure in solution. Incredibly high activity is achieved in the majority of cases including low catalytic loading and high temperatures, at industrially relevant conditions (180 °C 10,000:1:100 [LA]:[Zn]:[BnOH]), with high conversion achieved within 10 minutes and TOFs in excess of 100,000 hr-1 achieved. The performance of these initiators for polymer production is supported by GPC, DSC and IR spectroscopy which all highlight the excellent control achieved.

AB - A range of simple ethylenediamine based Zn(II) and Mg(II) complexes have been prepared and their structures determined via NMR spectroscopy and X-ray crystallography. Preparation of these complexes was also demonstrated to be scalable, with 25 g of Zn(1)2 being readily produced. These complexes were trialed for the ring opening polymerisation (ROP) of lactide under industrial relevant conditions. Their reactivity has been related to their structure in solution. Incredibly high activity is achieved in the majority of cases including low catalytic loading and high temperatures, at industrially relevant conditions (180 °C 10,000:1:100 [LA]:[Zn]:[BnOH]), with high conversion achieved within 10 minutes and TOFs in excess of 100,000 hr-1 achieved. The performance of these initiators for polymer production is supported by GPC, DSC and IR spectroscopy which all highlight the excellent control achieved.

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