High-utilisation nanoplatinum catalyst (Pt@cPIM) obtained via vacuum carbonisation in a molecularly rigid polymer of intrinsic microporosity

Yuanyang Rong, Daping He, Richard Malpass-Evans, Mariolino Carta, Neil B. McKeown, Murilo F. Gromboni, Lucia H. Mascaro, Geoffrey W. Nelson, John S. Foord, Philip Holdway, Sara E. C. Dale, Simon Bending, Frank Marken

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Polymers of intrinsic microporosity (PIM or here PIM-EA-TB) offer a highly rigid host environment into which hexachloroplatinate(IV) anions are readily adsorbed and vacuum carbonised (at 500 °C) to form active embedded platinum nanoparticles. This process is characterised by electron and optical microscopy, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and electrochemical methods, which reveal that the PIM microporosity facilitates the assembly of nanoparticles of typically 1.0 to 2.5-nm diameter. It is demonstrated that the resulting carbonised “Pt@cPIM” from drop-cast films of ca. 550-nm average thickness, when prepared on tin-doped indium oxide (ITO), contain not only fully encapsulated but also fully active platinum nanoparticles in an electrically conducting hetero-carbon host. Alternatively, for thinner films (50–250 nm) prepared by spin coating, the particles become more exposed due to additional loss of the carbon host. In contrast to catalyst materials prepared by vacuum-thermolysed hexachloroplatinate(IV) precursor, the platinum nanoparticles within Pt@cPIM retain high surface area, electrochemical activity and high catalyst efficiency due to the molecular rigidity of the host. Data are presented for oxygen reduction, methanol oxidation and glucose oxidation, and in all cases, the high catalyst surface area is linked to excellent catalyst utilisation. Robust transparent platinum-coated electrodes are obtained with reactivity equivalent to bare platinum but with only 1 μg Pt cm−2 (i.e. ~100% active Pt nanoparticle surface is maintained in the carbonised microporous host). [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)132-143
Number of pages12
JournalElectrocatalysis
Volume8
Issue number2
Early online date12 Dec 2016
DOIs
Publication statusPublished - 1 Mar 2017

Fingerprint

Microporosity
Carbonization
Platinum
Polymers
Vacuum
Nanoparticles
Catalysts
Carbon
Oxidation
Tin
Spin coating
Rigidity
Indium
Electron microscopy
Optical microscopy
Anions
Glucose
Methanol
Atomic force microscopy
Negative ions

Keywords

  • Encapsulation
  • Fuel cell
  • Nanocatalyst
  • Noble metal
  • One-step synthesis
  • Voltammetry

Cite this

High-utilisation nanoplatinum catalyst (Pt@cPIM) obtained via vacuum carbonisation in a molecularly rigid polymer of intrinsic microporosity. / Rong, Yuanyang; He, Daping; Malpass-Evans, Richard; Carta, Mariolino; McKeown, Neil B.; Gromboni, Murilo F.; Mascaro, Lucia H.; Nelson, Geoffrey W.; Foord, John S.; Holdway, Philip; Dale, Sara E. C.; Bending, Simon; Marken, Frank.

In: Electrocatalysis, Vol. 8, No. 2, 01.03.2017, p. 132-143.

Research output: Contribution to journalArticle

Rong, Y, He, D, Malpass-Evans, R, Carta, M, McKeown, NB, Gromboni, MF, Mascaro, LH, Nelson, GW, Foord, JS, Holdway, P, Dale, SEC, Bending, S & Marken, F 2017, 'High-utilisation nanoplatinum catalyst (Pt@cPIM) obtained via vacuum carbonisation in a molecularly rigid polymer of intrinsic microporosity', Electrocatalysis, vol. 8, no. 2, pp. 132-143. https://doi.org/10.1007/s12678-016-0347-5
Rong, Yuanyang ; He, Daping ; Malpass-Evans, Richard ; Carta, Mariolino ; McKeown, Neil B. ; Gromboni, Murilo F. ; Mascaro, Lucia H. ; Nelson, Geoffrey W. ; Foord, John S. ; Holdway, Philip ; Dale, Sara E. C. ; Bending, Simon ; Marken, Frank. / High-utilisation nanoplatinum catalyst (Pt@cPIM) obtained via vacuum carbonisation in a molecularly rigid polymer of intrinsic microporosity. In: Electrocatalysis. 2017 ; Vol. 8, No. 2. pp. 132-143.
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abstract = "Polymers of intrinsic microporosity (PIM or here PIM-EA-TB) offer a highly rigid host environment into which hexachloroplatinate(IV) anions are readily adsorbed and vacuum carbonised (at 500 °C) to form active embedded platinum nanoparticles. This process is characterised by electron and optical microscopy, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and electrochemical methods, which reveal that the PIM microporosity facilitates the assembly of nanoparticles of typically 1.0 to 2.5-nm diameter. It is demonstrated that the resulting carbonised “Pt@cPIM” from drop-cast films of ca. 550-nm average thickness, when prepared on tin-doped indium oxide (ITO), contain not only fully encapsulated but also fully active platinum nanoparticles in an electrically conducting hetero-carbon host. Alternatively, for thinner films (50–250 nm) prepared by spin coating, the particles become more exposed due to additional loss of the carbon host. In contrast to catalyst materials prepared by vacuum-thermolysed hexachloroplatinate(IV) precursor, the platinum nanoparticles within Pt@cPIM retain high surface area, electrochemical activity and high catalyst efficiency due to the molecular rigidity of the host. Data are presented for oxygen reduction, methanol oxidation and glucose oxidation, and in all cases, the high catalyst surface area is linked to excellent catalyst utilisation. Robust transparent platinum-coated electrodes are obtained with reactivity equivalent to bare platinum but with only 1 μg Pt cm−2 (i.e. ~100{\%} active Pt nanoparticle surface is maintained in the carbonised microporous host). [Figure not available: see fulltext.]",
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AU - Carta, Mariolino

AU - McKeown, Neil B.

AU - Gromboni, Murilo F.

AU - Mascaro, Lucia H.

AU - Nelson, Geoffrey W.

AU - Foord, John S.

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